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A new diradical based on diindenocarbazole or difluorenopyrrole was synthesized and experimentally characterized by optical, electrochemical, and magnetic techniques, as well as quantum chemical calculations. The isomerism of these structures tunes the diradical character and the associated properties, representing a unique case of such important modulation. A full study of the electronic structure was carried out considering the perturbative interactions between different canonical forms as well as the anti-aromatic character of the molecular cores. Such a study reveals how we can tune diradical character simply by reorganizing the bonding patterns at constant chemical costs (composition).
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An organometallic nickel complex containing thieno[3,2-b]thiophene units was designed and synthesized. Composite films of the resulting nickel complex and polyvinylidene difluoride, which can be fabricated via a simple solution process under atmospheric conditions, exhibit remarkably high n-type conductivity (>200 S cm-1). Moreover, the thermoelectric power factor of the n-type composite film was proven to be air stable. A grazing-incidence wide-angle X-ray diffraction analysis indicated a significant impact of introducing the thieno[3,2-b]thiophene core into the backbone of the nickel complex on the orientation within the composite films.
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The device efficiency of PM6:Y6-based nonfullerene organic solar cells is fast advanced recently. To maintain organic solar cells (OSCs) with high power conversion efficiency over 16% in long-term operation, however, remains a challenge. Here, a novel non-volatile additive, an open-cage [60]fullerene (8OC60Me), is incorporated into PM6:Y6-based OSCs for high-performance with high durability. With optimized addition of 1.0 wt % 8OC60Me, the PCE value of PM6:Y6/8OC60Me OSCs can be promoted to 16.5% from 15.0%. Most strikingly, such a high PCE performance can maintain nearly 100% for over 500 h at room temperature; at an elevated operation temperature of 80 °C, the PCE can be stabilized above 15.0% after 45 h of operation. Grazing incidence small- and wide- angle X-ray scattering studies reveal improved orientation and crystallinity of Y6 in a fractal-like network structure of PM6 in PM6:Y6/8OC60Me films under in situ annealing, parallel to the enhanced electron mobility. Analysis of charge distributions lines up possible van der Waals interaction between the thienyl/carbonyl moiety of 8OC60Me and difluorophenyl-based FIC-end groups of Y6. This result is of great contrast to those devices with the best-selling PC61BM as the additivesâ8OC60Me might be of interest to be incorporated into future Y6-based OSCs for concomitantly improved PCE and excellent stability.
RESUMO
In this study, we designed, synthesized, and characterized an A-D-A'-D-A-type indacenodithienothiophene (IDTT)-based molecular acceptor that exhibited a broader absorption range and higher lowest unoccupied molecular orbital energy level with a nearly comparable band gap compared to a well-known electron acceptor IT-M. The designed electron-deficient molecular acceptor FB-2IDTT-4Cl with a fluorinated benzene tether (FB), that is, p-tetrafluorophenylene divinylene, demonstrated long-wavelength absorption and high hole and electron charge mobility in the thin films blended with the electron donor PBDB-T for an inverted organic photovoltaic (OPV) binary device, resulting in a maximum power conversion efficiency (PCE) of 11.4%. Such a performance is comparably as high as that of the device with PBDB-T:IT-M, and particularly, it was 18.8% higher than that of the devices with ITIC-4Cl as the acceptor (PCE 9.1% ± 0.5%) and 24.9% higher than that of the devices with the thiophene-flanked benzothiadiazole-bridged acceptor CNDTBT-IDTT-FINCN (PCE 9.01% ± 0.13%). Furthermore, varying the illumination intensity from 200 to 2000 lux increased the Jsc and Voc values as well as the FF values, thus leading to increased PCE levels. In addition, the best PCE of the PM6:Y6 device with 1% FB-2IDTT-4Cl as additives was 16.9%. Our stability test showed that the PM6:Y6 standard device efficiency downgraded very soon either at room temperature or under thermal-annealing conditions. However, with the addition of 1% FB-2IDTT-4Cl as additives, the device efficiency still can be maintained at 90-95% in 500 h at room temperature and 95% at 20 h and 85-95% in 45 h at an annealing temperature of 80 °C. These findings demonstrate FB-2IDTT-4Cl to be a promising candidate as an electron acceptor with a fluorinated π-bridging fused-ring design for OPV applications.
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A domino-type multiple C-H functionalization of tetracene with molecular benzene is reported. Under the typical conditions of the Scholl reaction, a domino reaction occurs between tetracene and six molecules of benzene in one pot to furnish an aromatic compound with a curved π-system. This reaction sequence involves oxidative cross-dehydrogenative coupling/annulation and Friedel-Crafts-type reactions. Eight C-C bonds are formed via this intermolecular domino reaction without mediation by a metal or the assistance of a specific substituent.
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Difluoreno[4,3-b:3',4'-d]furan (DFFu) was prepared via a short, scalable, multi-step synthesis, and characterized by crystallography, spectroscopic measurements, and theoretical calculations. Even though the results revealed an open-shell singlet diradical character, DFFu is stable under ambient conditions. The radical cationic and dianionic species of DFFu were also synthesized and characterized.
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A facile method for the direct cross-annulation of unfunctionalized tetracene is reported. The one-pot oxidative cross-dehydrogenative coupling (CDC) between tetracene and aromatic compounds, such as benzene or 2-methylthiophene, furnished annulated products with an extended π-network. Moreover, relative to the benzo-annulated tetracenes, thieno-annulated tetracenes exhibited notably improved photooxidative stability. This behavior stands in sharp contrast with that of tetracene and its derivatives, such as rubrene, which readily engage in photoinduced oxidation reactions.
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Near- and mid-IR absorption spectra of endohedral H2@C60+ have been measured using He-tagging. The samples have been prepared using a "molecular surgery" synthetic approach and were ionized and spectroscopically characterized in the gas phase. In contrast to neutral C60 and H2@C60, the corresponding He-tagged cationic species show distinct spectral differences. Shifts and line splittings in the near- and mid-IR regions indicate the influence of the caged hydrogen molecule on both the electronic ground and excited states. Possible relevance to astronomy is discussed.
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The palladium-catalyzed cyclization on the fullerene C60 cage has been achieved using several aryl halides and C60. This reaction was found to be accelerated by the addition of pivalic acid, which can be rationally explained by the computational study based on the concerted metalation-deprotonation mechanism. We also demonstrated the regioselective π-functionalization using prefunctionalized designed molecules possessing the same substructure on the C60 cage. The single crystal X-ray analysis and electrostatic potential map revealed that the orientation of entrapped H2O inside the naphthalene-fused open-cage C60 derivative is electrostatically demanded due to the naphthalene-fusion and construction of the opening.
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To investigate the intrinsic reactivity of atomic nitrogen, which had previously been accomplished only by examining its decay in the gas phase using special equipment, a nitrogen atom was inserted into a series of molecule-encapsulating C60 and C70 fullerenes. Among the studied endofullerenes, H2 @C70 was able to encapsulate an additional nitrogen atom within the fullerene cage under radiofrequency plasma conditions. The product was analyzed by ESR spectroscopy and mass spectrometry in solution, which revealed that the nitrogen atom with a quartet ground state does not react but weakly interact with the H2 molecule, thus demonstrating the utility of such fullerenes as "nanoflasks".
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Dissociation of an acid molecule in aqueous media is one of the most fundamental solvation processes but its details remain poorly understood at the distinct molecular level. Conducting high-pressure treatments of an open-cage fullerene C70 derivative with hydrogen fluoride (HF) in the presence of H2O, we achieved an unprecedented encapsulation of H2O·HF and H2O. Restoration of the opening yielded the endohedral C70s, that is, (H2O·HF)@C70, H2O@C70, and HF@C70 in macroscopic scales. Putting an H2O·HF complex into the fullerene cage was a crucial step, and it would proceed by the synergistic effects of "pushing from outside" and "pulling from inside." The structure of the H2O·HF was unambiguously determined by single crystal x-ray diffraction analysis. The nuclear magnetic resonance measurements revealed the formation of a hydrogen bond between the H2O and HF molecules without proton transfer even at 140°C.
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Even though the Scholl reaction is one of the most powerful processes for the synthesis of polycyclic aromatic hydrocarbons (PAHs), its mechanism still remains a subject of discussion. Herein, we report a unique twofold Scholl cyclization of a 5,11-dinaphthyltetracene. Single-crystal X-ray diffraction analysis of the cyclization product revealed that unsymmetric cyclizations of the two naphthyl groups resulted in the formation of fully unsaturated pentagonal and hexagonal rings. The thus obtained product exhibits a twisted π-surface and an absorption band that reaches up to 950â nm. A combined experimental and theoretical study showed that such unsymmetric Scholl cyclizations can be rationalized in terms of a mechanism that involves dicationic intermediates, which stands in contrast to previously reported pathways based on radical cations and arenium ions.
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A hydrogen-bonding network is a key impelling force for an assembly in bulk water. The fullerene cage can incarcerate a water molecule without hydrogen-bonding. Herein, we focused on spin system H2O@C59N·. The 1H NMR relaxation time of entrapped H2O was significantly reduced by the paramagnetic effect. Interestingly, the electron affinity and ionization energy were suggested to vary depending on the orientation of entrapped H2O owing to the degree of the partial charge transfer from entrapped H2O to C59N·.
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A supramolecular complex was constructed by encapsulation of a 3 O2 molecule inside an open-cage C60 derivative. Its single-crystal X-ray diffraction analysis revealed the presence of the 3 O2 at the center of the fullerene cage. The CV measurements suggested that unprecedented dehydrogenation was promoted by the encapsulated 3 O2 after two-electron reduction. The ESR measurements displayed the triplet character as well as the anisotropy of the 3 O2 . Additionally, the SQUID measurements also demonstrated the paramagnetic behavior above 3â K without an antiferromagnetic transition. Upon photoirradiation with visible light, three phosphorescent bands at the NIR region were observed, arising from the exited 1 O2 generated by self-sensitization with the outer cage, whose lifetimes were not affected by the environments. These studies confirmed that the complex is a crystalline triplet system with incompatible "high spin density" but "small interspin interaction" properties.
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Methanol (CH3 OH) and formaldehyde (H2 CO) molecules were inserted into an open-cage C60 derivative with a large opening, under high-pressure and high-temperature conditions in solution. Isolation of their molecular complexes in pure form was achieved by the use of recycling HPLC with Buckyprep columns. 1 Hâ NMR spectroscopy, single-crystal X-ray diffraction studies, and DFT calculations revealed the orientation of the encapsulated CH3 OH and H2 CO, both in solution and in the solid state, and the results show that the CH3 group of the CH3 OH and the carbonyl group of the H2 CO point to the bottom of the cages. Furthermore, the dynamic behavior of the CH3 OH and H2 CO were studied at the molecular level.
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Upon irradiation of a sulfoxide C60 derivative with a 17-membered-ring opening, rearrangement of the carbon framework took place to give an unprecedented lactone C60 derivative with a 14-membered-ring opening, whose structure was unambiguously determined by single crystal X-ray analysis. This reaction is completely different from that of the previously reported sulfoxide C60 and C70 derivatives with a 13-membered-ring opening.
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A synthetic route to dithieno-fused CP-PAHs with a pyracylene segment is reported. A combination of experimental and theoretical studies revealed a strong contribution of antiaromatic character to the electronic structure of this dithieno-fused CP-PAH. Anisotropy of current-induced density (ACID) calculations indicated a significantly increased paramagnetic ring current on the two pentagonal rings, which is more prominent than that of the dibenzo-fused analogue. Furthermore, enhanced electron affinity and a consequently decreased HOMO-LUMO gap were observed for this dithieno-fused CP-PAH.
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4,7-Bis-[3-(dimesitylboryl)thien-2-yl]benzothiadiazole (1) and monoborylated derivative 2 were synthesized and their chromic behavior was investigated. Photophysical measurements, single-crystal XRD analysis, and theoretical calculations revealed that an intramolecular B-N coordination bond formed reversibly. The equilibrium of this reversible bond formation depends on the solid-state structure, solvent, temperature, and mechanical forces, and leads to significant changes in the electronic structure and chromic behavior of these molecules. The responsiveness toward external stimuli, resulting in the reversible formation of open and closed forms of this system, is achieved through weak intramolecular B-N coordination bonds induced by the steric bulk of the mesityl groups on the boron centers.
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The removal of addends on the fullerene C60 cage plays an important role in the final stage for synthesizing endohedral fullerenes by the molecular surgery method. We developed a cobalt-mediated reaction to regenerate C60 from N-substituted C60 derivatives (aziridinofullerene and azafulleroid). In these reactions, we found the formation of a green monovalent-cobalt complex of C60, and its structure was unambiguously determined by X-ray analysis. The characteristic electronic structure of this cobalt complex was studied by IR and UV-vis absorption spectroscopy and electrochemical analyses.
RESUMO
The concept of the bond polarization is a useful tool to understand chemical reactions and fundamental properties of compounds. However, experimental considerations are limited owing to its difficulty of reliable description. We demonstrated that geometrically isolated H2 O inside the cage of fullerene C60 is a possible probe to evaluate the polarization degree of covalent bonds C(C60 )-X (X=heteroatom) on the C60 cage. The 1 Hâ NMR relaxation times of entrapped H2 O have been systematically measured at variable temperatures for H2 O@C60 X (X=CR2 , NR, O, and O2 ). The results followed in the order of electronegativities of C (2.55), N (3.04), and O (3.44), indicating that entrapped H2 O can sensitively respond to the degree of the bond polarization.