Elucidating the modified performance of high nuclearity of Cu nanostructures-PTFE thin film.

The aim of this study is to attain an extensive insight on the performance mechanism that is associated with the formation of Cu nanostructures- polytetrafluoroethylene (PTFE) thin film. The work presented Cu nanostructures synthesised via microwave-assisted method at different Cu precursor concentrations to observe the influence of different average particle diameter distribution, [Formula: see text] of Cu nanostructures on the fabricated Cu nano thin film. The thin films of Cu nanostructures with a layer of PTFE were fabricated using the Meyer rod coating method. Evaluating the effect of Cu nanostructures at different [Formula: see text] with overcoated PTFE layer showed that the resistance of fabricated thin film coated with PTFE is not significantly different from that of the uncoated thin film. The results implicate the influence of the PTFE layer towards the output performance, which can maintain a stable and constant resistance over time without affecting the original properties of pure Cu nanostructures, although some of the Cu nanostructures seep into the layer of PTFE. The novelty of this study lies in the effect of the intrinsic interaction between the layer of Cu nanostructure and PTFE, which modulate the performance, especially in photovoltaic cell application.

The physical and optical investigations of the tannic acid functionalised Cu-based oxide nanostructures.

The need for a mild, low-cost, green environment that is able to produce exotic properties of output nanostructures is appealing nowadays. Employing these requirements, the copper (Cu)-based oxide nanostructures have been successfully synthesised via one-pot reaction using biocompatible natural polyphenol, tannic acid (TA) as both the reducing agent and stabiliser at 60, 70 and 80 °C. The structural and optical studies disclosed the effect of TA on the surface morphology, phase purity, elemental composition, optical microstrain and optical intrinsic energy of this mixed Cu2O and CuO nanostructures. The optically based method describes the comparative details of the multi-band gap in the presence of more than one element with overlapping spectra from the first-derivative absorbance curve [Formula: see text] and the exponential absorbance of Urbach tail energy [Formula: see text] towards the conventional Tauc bandgap. The [Formula: see text] demonstrates that the pronounced effect of TA that Cu2O and CuO nanostructures creates much sensitive first-derivative bandgap output compared to the Tauc bandgap. The results also show that the [Formula: see text] reduced as the temperature reaches 70 °C and then experienced sudden increase at 80 °C. The change in the pattern is parallel to the trend observed in the Williamson-Hall microstrain and is evident from the variations of the mean crystallite size [Formula: see text] which is also a cause response to the change in temperature or pH. Therefore, the current work has elucidated that the structural and optical correlations on the as-synthesised Cu2O and CuO nanostructures in the presence of TA were the combined reaction of pH change and the ligand complexation reactions. The acquired results suggest a more comprehensive range of studies to further understand the extent relationship between the physical and optical properties of TA functionalised Cu-based oxide nanostructures.