Transport, trapping, triplet fusion: thermally retarded exciton migration in tetracene single crystals.

Efficient exciton migration is crucial for optoelectronic organic devices. While the transport of triplet excitons is generally slow compared to singlet excitons, triplet exciton migration in certain molecular semiconductors with endothermic singlet fission appears to be enhanced by a time-delayed regeneration of the more mobile singlet species via triplet fusion. This combined transport mechanism could be exploited for devices, but the interplay between singlet fission and triplet fusion, as well as the role of trap states is not yet well understood. Here, we study the spatiotemporal exciton dynamics in the singlet fission material tetracene by means of time resolved photoluminescence micro-spectroscopy on crystalline samples of different quality. Varying the temperature allows us to modify the dynamic equilibrium between singlet, triplet and trapped excitons. Supported by a kinetic model, we find that thermally activated dissociation of triplet pairs into free triplet excitons can account for an increase of the diffusion length below room temperature. Moreover, we demonstrate that trapping competes efficiently with exciton migration.

A New Family of Layered Metal-Organic Semiconductors: Cu/V-Organophosphonates.

Herein, we report the design and synthesis of a layered redox-active, antiferromagnetic metal organic semiconductor crystals with the chemical formula [Cu(H2 O)2 V(µ-O)(PPA)2 ] (where PPA is phenylphosphonate). The crystal structure of [Cu(H2 O)2 V(µ-O)(PPA)2 ] shows that the metal phosphonate layers are separated by phenyl groups of the phenyl phosphonate linker. Tauc plotting of diffuse reflectance spectra indicates that [Cu(H2 O)2 V(µ-O)(PPA)2 ] has an indirect band gap of 2.19 eV. Photoluminescence (PL) spectra indicate a complex landscape of energy states with PL peaks at 1.8 and 2.2 eV. [Cu(H2 O)2 V(µ-O)(PPA)2 ] has estimated hybrid ionic and electronic conductivity values between 0.13 and 0.6 S m-1 . Temperature-dependent magnetization measurements show that [Cu(H2 O)2 V(µ-O)(PPA)2 ] exhibits short range antiferromagnetic order between Cu(II) and V(IV) ions. [Cu(H2 O)2 V(µ-O)(PPA)2 ] is also photoluminescent with photoluminescence quantum yield of 0.02%. [Cu(H2 O)2 V(µ-O)(PPA)2 ] shows high electrochemical, and thermal stability.

Wigner crystallization of single photons in cold Rydberg ensembles.

The coupling of weak light fields to Rydberg states of atoms under conditions of electromagnetically induced transparency leads to the formation of Rydberg polaritons which are quasiparticles with tunable effective mass and nonlocal interactions. Confined to one spatial dimension their low energy physics is that of a moving-frame Luttinger liquid which, due to the nonlocal character of the repulsive interaction, can form a Wigner crystal of individual photons. We calculate the Luttinger K parameter using density-matrix renormalization group simulations and find that under typical slow-light conditions kinetic energy contributions are too strong for crystal formation. However, adiabatically increasing the polariton mass by turning a light pulse into stationary spin excitations allows us to generate true crystalline order over a finite length. The dynamics of this process and asymptotic correlations are analyzed in terms of a time-dependent Luttinger theory.

Dynamical simulation of integrable and nonintegrable models in the Heisenberg picture.

The numerical simulation of quantum many-body dynamics is typically limited by the linear growth of entanglement with time. Recently numerical studies have shown that for 1D Bethe-integrable models the simulation of local operators in the Heisenberg picture can be efficient. Using the spin-1/2 XX chain as generic example of an integrable model that can be mapped to free fermions, we provide a simple explanation for this. We show furthermore that the same reduction of complexity applies to operators that have a high-temperature autocorrelation function which decays slower than exponential, i.e., with a power law. Thus efficient simulability may already be implied by a single conservation law as we will illustrate numerically for the spin-1 XXZ model.

Dynamics of pair correlations in the attractive Lieb-Liniger gas.

We investigate the dynamics of a one-dimensional Bose gas after a quench from the Tonks-Girardeau regime to the regime of strong attractive interactions applying analytical techniques and numerical simulations. After the quench the system is found to be predominantly in an excited gaslike state, the so-called super-Tonks gas, however with a small coherent admixture of two-particle bound states. Despite its small amplitude, the latter leads to a pronounced oscillation of the local density correlation with a frequency corresponding to the binding energy of the pair. Contributions from bound states with larger particle numbers are found to be negligible.