Outstanding Room-Temperature Hydrogen Gas Detection by Plasma-Assisted and Graphene-Functionalized Core-Shell Assembly of SnO2 Nanoburflower.

Here, we have reported the synthesis of three-dimensional, mesoporous, nano-SnO2 cores encapsulated in nonstoichiometric SnO2 shells grown by chemical as well as physical synthesis procedures such as plasma-enhanced chemical vapor deposition, followed by functionalization with reduced graphene oxide (rGO) on the surface. The main motif to fabricate such morphology, i.e., core-shell assembly of burflower-like SnO2 nanobid is to distinguish gases quantitatively at reduced operating temperatures. Electrochemical results reveal that rGO anchored on SnO2 surface offers excellent gas detection performances at room temperature. It exhibits outstanding H2 selectivity through a wide range, from ∼10 ppm to 1 vol %, with very little cross-sensitivity against other similar types of reducing gases. Good recovery as well as prompt responses also added flair in its quality due to the highly mesoporous architecture. Without using any expensive dopant/catalyst/filler or any special class of surfactants, these unique SnO2 mesoporous nanostructures have exhibited exceptional gas sensing performances at room temperature and are thus helpful to fabricate sensing devices in most cost-effective and eco-friendly manner.

Sonochemical synthesis and properties of nanoparticles of FeSbO4.

A sonochemical method was employed to prepare reactive nanoparticles of FeSbO(4) at 300 °C, which is the lowest calcination temperature reported so far for preparing FeSbO(4). A systematic evolution of the FeSbO(4) phase formation as a function of temperature was monitored by in situ synchrotron X-ray measurements. The 300 and 450 °C calcined powders exhibited specific surface areas of 116 and 75 m(2)/g, respectively. The X-ray photoelectron spectra analysis confirmed the presence of mainly Fe(3+) and Sb(5+) in the calcined powder. The response of the fabricated sensors (using both 300 and 450 °C calcined powders) toward 1000 ppm and 1, 2, 4, and 8% hydrogen, respectively, has been monitored at various operating temperatures. The sensors fabricated using 300 °C calcined powder exhibited a response of 76% toward 4% H(2) gas at an operating temperature of 300 °C, while those fabricated using 450 °C calcined powder exhibited a higher response of 91% with a quick recovery toward 4% H(2) gas at 300 °C. The results confirmed that a higher calcination temperature was preferred to achieve better sensitivity and selectivity toward hydrogen in comparison to other reducing gases such as butane and methane. The experimental results confirmed that the sonochemical process can be easily used to prepare FeSbO(4) nanoparticles for various catalytic applications as demonstrated. Here, we project FeSbO(4) as a new class of material exhibiting high sensitivity toward a wide range of hydrogen gas. Such sensors that could detect high concentrations of hydrogen may find application in nuclear reactors where there will be a leakage of hydrogen.