Microwave hydrothermal preparation of reduced graphene oxide-induced p-AgO/n-MoO3 heterostructures for enhanced photocatalytic activity through S-scheme mechanism and its electronic performance.

Through a powerful and modest closed system Microwave hydrothermal process, a methodological analysis is made in the rational synthesis of the reduced graphene oxide-induced p-AgO/n-MoO3 (RGAM) heterostructures. These have strong p-n junction heterostructures with considerable electron-hole recombination functioning as solar catalysts. The enhanced photocatalytic activity through the plasmonic step scheme (S-scheme mechanism) describes the effective charge recombination process. The energy band positions, bandgap, and work function are determined to understand the Fermi level shifts; this describes the S-scheme mechanism by UPS analysis which assessed an electron transfer between AgO and MoO3, yielding work function values of 6.34 eV and 6.62eV, respectively. This photocatalytic activity aids in dye removal by 94.22%, and heavy metals such as chromium (Cr) are eliminated by the surface action of sunlight on the produced material during solar irradiation. Electrochemical studies such as photocurrent response, cyclic voltammogram, and electrochemical impedance spectroscopy for RGAM heterostructures were also carried out. The study helps to broaden the search for and development of new hybrid carbon composites for electrochemical applications.