RESUMO
Materials exhibiting room temperature phosphorescence (RTP) are in high demand for signage, information encryption, sensing, and biological imaging. Due to weak spin-orbit coupling and other non-radiative processes that effectively quench the triplet excited states, RTP is sparsely observed in organic materials. Although the incorporation of a heavy atom through covalent or non-covalent modification circumvents these drawbacks, heavy-atom-containing materials are undesirable because of their deleterious side effects. Here, we designed and synthesized a new naphthalidenimine-boron complex as a coating material for the single crystals of 4,4'-dimethoxybenzophenone. The coated surface was observed to exhibit yellowish-green phosphorescence with ms lifetimes at ambient conditions through Förster resonance energy transfer (FRET). Importantly, the mechanical flexibility of the single crystals was observed to be retained after coating. The fluorescence-phosphorescence dual emission was utilised for colour-tunable optical waveguiding and anti-counterfeiting applications. As organic single crystals that can sustain mechanical deformations are emerging as the next-generation materials for electronic device fabrication, the flexible RTP organic crystals showing colour-tuneable optical waveguiding could be omnipotent in electronics.
RESUMO
Organic crystals that respond to external stimuli are interesting for the design of smart materials. Here, we show that molecular engineering can transform simple naphthalidenimine-boron complexesâknown for their exciting photophysical propertiesâinto functional materials that exhibit thermosalience and thermal-luminescence switching. Detailed crystallographic and spectroscopic investigations revealed the role of subtle molecular parameters in deciphering charge-transfer interactions, which in turn imparted dynamic properties to the crystals. The simultaneous observation of thermally induced jumping and luminescence switching makes these crystals ideal for optoelectronic applications.
RESUMO
The design of molecular compounds that exhibit flexibility is an emerging area of research. Although a fair amount of success has been achieved in the design of plastic or elastic crystals, realizing multidimensional plastic and elastic bending remains challenging. We report herein a naphthalidenimine-boron complex that showed size-dependent dual mechanical bending behavior whereas its parent Schiff base was brittle. Detailed crystallographic and spectroscopic analysis revealed the importance of boron in imparting the interesting mechanical properties. Furthermore, the luminescence of the molecule was turned-on subsequent to boron complexation, thereby allowing it to be explored for multimode optical waveguide applications. Our in-depth study of the size-dependent plastic and elastic bending of the crystals thus provides important insights in molecular engineering and could act as a platform for the development of future smart flexible materials for optoelectronic applications.
RESUMO
The synthesis of water-soluble chitosan nanocomposites incorporating BODIPY and the investigation of their photosensitization properties is reported. It was observed that the singlet oxygen generation capability of nanocomposites containing a mixture of BODIPY and iodine-containing molecules are higher than that of the nanocomposites containing BODIPY alone. It is hypothesized that the supramolecular interactions between BODIPY and iodine-containing molecules confined within the nanocomposites lead to the enhanced singlet oxygen generation.
