Synergistic adsorption and kinetic studies of heterostructured g-C3N4/TiO2 nano-photocatalyst under visible light for enhanced CO2 reduction.

Graphitic carbon nitride (g-C3N4) and titanium dioxide (TiO2) were synthesized using sol-gel and ultrasonic impregnation technique followed by calcination for photocatalytic CO2 reduction. The nano-photocatalysts were analyzed for their morphological, structural, and optical characteristics. Scanning electron microscopy (SEM) revealed the presence of spherical and layered sheet-like nanoparticles, as well as the occurrence of minor aggregations. The ultraviolet-visible spectroscopy (UV-vis) revealed that g-C3N4 has good photocatalytic properties with a medium band gap (2.7 eV), and TiO2 has high charge transfer potentials, robust oxidation properties, and high band gap (3.20 eV). However, the larger band gap makes it unresponsive in the visible light spectrum. In order to circumvent this constraint, a hybrid heterostructured g-C3N4/TiO2 catalyst with different compositions, viz., 1:1, 1:2, and 2:1, were fabricated using the ultrasonic impregnation technique followed by calcination process. The optical band gap of g-C3N4/TiO2 nanocomposite shows a red shift towards 2.85 eV from 3.20 eV for bare TiO2, inferring enhanced absorption in the visible light region. Further, the photocatalytic experiments were performed using visible light sources for all the catalysts. The g-C3N4/TiO2 (2:1) reported higher photocatalytic activity due to its reduced crystallite size of 12.94 nm which were investigated using X-ray diffraction analysis (XRD) and lower band gap of 2.85 eV. The study infers that hybrid photocatalyst enhances the visible light absorption, electron-hole (e - /h +) pair separation rate, and photocatalytic reduction of CO2. In addition, two adsorption models Langmuir and Freundlich were used and adsorption kinetic data were fitted to pseudo-first-order reaction for all the five catalysts. The adsorption isotherm of CO2 by g-C3N4/TiO2 (2:1) well fitted by the Freundlich adsorption equation. On the basis of adsorption magnitude (n) values (1.74), it was found that the interaction between CO2 molecules and g-C3N4/TiO2 occurs according to the chemisorption mechanism. The kinetic study infers that the highest value of apparent rate constant (kapp) was exhibited by g-C3N4/TiO2 (2:1), which indicates that the products predominate at equilibrium.

Carbon credit reduction: A techno-economic analysis of "drop-in" fuel production.

The current study elucidates the fundamentals of technical, financial, and environmental viability of the processes used for sustainable "drop-in" fuel generation. At present, the price of producing "drop-in" fuels is around two times as costly (5-6 USD/gallon) as the cost of fossil fuels (3 USD/gallon), especially when using second-generation feedstocks. Hence, this necessitates a comprehensive techno-economic understanding of the current technologies with respect to "drop-in"-fuel. This entitles technical-economic viability, and environmental sustainability to make the processes involved commercially viable. In this context, the present review addresses unique contrasts among the various processes involved in "drop-in" fuel production. Furthermore, principles and process flow of techno-economic analysis as well as environmental implications in terms of reduced carbon footprint and carbon credit are elucidated to discuss fundamentals of techno-economic analysis in terms of capital and operational expenditure, revenue, simulation, cash flow analysis, mass and energy balances with respect to evidence-based practices. Case specific techno-economic studies with current developments in this field of research with emphasis on software tools viz., Aspen Plus, Aspen HYSIS, Aspen Plus Economic Analyser (APEC) Aspen Icarus Process Evaluator (AIPE) are also highlighted. The study also emphasis on the carbon foot print of biofuels and its carbon credits (Carbon Offset Credits (COCs) and Carbon Reduction Credits (CRCs)) by leveraging a deep technical and robust business-oriented insights about the techno-economic analysis (TEA) exclusively for the biofuel production.