1.
Preparation of Peapod Polymer via the Supramolecular Chain Formation by Tris(spiroborate) Twin Bowl.
ACS Macro Lett
; 6(1): 62-65, 2017 Jan 17.
Artigo
em Inglês
| MEDLINE
| ID: mdl-35651106
RESUMO
Successive guest-containing tubular polymer was prepared by the olefin metathesis polymerization of tris(spiroborate) twin bowl after the formation of supramolecular polymer. The cationic iridium(III) complexes were topologically fixed inside the polymer to form a peapod-like structure. The polymer was evaluated by SEC, ICP-AES, and DLS analyses, and string-like structures were found in the AFM observation of the peapod polymer.