Swing Origami-Structure-Based Triboelectric Nanogenerator for Harvesting Blue Energy toward Marine Environmental Applications.

The appearance of triboelectric nanogenerators (TENG) provides a promising energy technology for harvesting abundant water wave energy. Here, the design and fabrication of a swinging origami-structured TENG (SO-TENG) tailored specifically for water wave energy harvesting are presented. The design incorporates an oscillating structure weighted at the bottom, inducing reciprocating motion propelled by the inertia of passing water waves. This reciprocating motion efficiently converts mechanical into electrical energy through the origami structure. By employing origami as the monomer structure, the surface contact area between friction layers is enhanced, thereby optimizing output performance. the swinging structure, combined with the placement of heavy objects, enhances the folding and contact of the origami, allowing it to operate effectively in low-frequency water wave environments. This configuration exhibits robust power generation capabilities, making it suitable for powering small electronic devices in water wave environments. Furthermore, when applied to metal corrosion protection, the SO-TENG demonstrates notable efficacy. Compared to exposed Q235 carbon steel, Q235 carbon steel protected by SO-TENG exhibits a significant reduction in open-circuit potential drop, approximately 155 mV, indicative of superior anti-corrosion properties. It lays a solid foundation for water wave energy collection and self-powered metal corrosion protection in marine environments.

Highly porous and rough polydimethylsiloxane film-based triboelectric nanogenerators and its application for electrochemical cathodic protection.

The development and utilization of triboelectric nanogenerator (TENG) are very important for realizing energy cleaning in electrochemical processes. However, limited electrical output performance plays a major stumbling block to this process. Herein, a porous and high-roughness PDMS (PR/PDMS) negative friction layer was obtained by doping PDMS with powdered chitosan and casting using a sacrificial anodic alumina template. A TENG was fabricated by the PR/PDMS with Al film (PR-TENG). The PR-TENG exhibited much better performance than the pure PDMS-based TENG, which was attributed to the porous properties of the PR/PDMS. Under the driving of external mechanical force at 5 Hz, the PR-TENG showed a maximum output open-circuit voltage (Voc) and short-circuit current density (Jsc) of 77.1 V and 33.9 mA/m2, respectively. To prove the concept, the electrochemical cathodic protection system with PR-TENG was constructed. Ultimately, the application prospects of the PR-TENG as a clean energy source for electrochemical processes were explored and evaluated.

Research progress of TiO2 photocathodic protection to metals in marine environment.

Corrosion protection has become an important issue as the amount of infrastructure construction in marine environment increased. Photocathodic protection is a promising method to reduce the corrosion of metals, and titanium dioxide (TiO2) is the most widely used photoanode. This review summarizes the progress in TiO2 photogenerated protection in recent years. Different types of semiconductors, including sulfides, metals, metal oxides, polymers, and other materials, are used to design and modify TiO2. The strategy to dramatically improve the efficiency of photoactivity is proposed, and the mechanism is investigated in detail. Characterization methods are also introduced, including morphology testing, light absorption, photoelectrochemistry, and protected metal observation. This review aims to provide a comprehensive overview of TiO2 development and guide photocathodic protection.