Improving acid mine drainage treatment by combining treatment technologies: A review.

The mining and processing of some minerals and coal result in the production of acid mine drainage (AMD) which contains elevated levels of sulfate and metals, which tend to pose serious environmental issues. There are different technologies that have been developed for the treatment of wastewater or AMD. However, there is no "one-size-fits-all" solution, hence a combination of available technologies should be considered to achieve effective treatment. In this review, AMD treatment technologies and the possible alignment in tandem of the different treatment technologies were discussed. The alignment was based on the target species of each technology and AMD composition. The choice of the technologies to combine depends on the quality of AMD and the desired quality of effluent depending on end use (e.g., drinking, industrial, irrigation or release into the environment). AMD treatment technologies targeting metals can be combined with membrane and/or ettringite precipitation technologies that focus on the removal of sulfates. Other technologies can be added to deal with the secondary waste products (e.g., sludge and brines) from the treatment processes. Moreover, some technologies such as ion exchange and adsorption can be added to target specific valuable elements in AMD. Such combinations have the potential to result in effective AMD treatment and minimum waste production, which are not easily achievable with the individual technologies. Overall, this review presents combinations of AMD treatment technologies which can work best together to produce optimal water quality and valuable products in a cost-effective manner.

Enhanced Solar Efficiency via Incorporation of Plasmonic Gold Nanostructures in a Titanium Oxide/Eosin Y Dye-Sensitized Solar Cell.

Plasmonic gold nanoparticles significantly improved the efficiency of a TiO2 and Eosin Y based dye-sensitized solar cell from 2.4 to 6.43%. The gold nanoparticles' sizes that were tested were 14 nm, 30 nm and 40 nm synthesized via the systematic reduction of citrate concentration using the Turkevich method. Prestine TiO2 without plasmonic gold nanoparticles yielded an efficiency of 2.4%. However, the loading of 40 nm gold nanoparticles into the TiO2 matrix yielded the highest DSSC efficiency of 6.43% compared to 30 nm (5.91%) and 14 nm (2.6%). The relatively high efficiency demonstrated by plasmonic gold nanoparticles is ascribed to light absorption/scattering, hot electron injection and plasmon-induced resonance energy transfer (PIRET), influenced by the size of the gold nanoparticles.

Laser Assisted Catalytic Growth of Silicon Nanowires Using Gold and Nickel Catalysts.

Laser assisted synthesis of silicon nanowires (SiNWs) was successfully achieved through the use of gold and nickel as catalysts. The diameter of the resulting SiNWs was found to be dependent on that of the catalyst in the case of gold catalyst. The gold catalysed silicon nanowires were unevenly curved and branched owing to the high kinetic energy possessed by gold nanoparticles (AuNPs) at relatively high processing temperature. The use of nickel as catalyst resulted in the formation of several SiNWs on a single nickel catalyst crystallite due to interconnection of the nickel metal crystallites at processing temperature. The morphology of SiNWs catalysed by both nickel and gold was controlled by optimising the laser energy during ablation.

Epitaxial deposition of silver ultra-fine nano-clusters on defect-free surfaces of HOPG-derived few-layer graphene in a UHV multi-chamber by in situ STM, ex situ XPS, and ab initio calculations.

The growth of three-dimensional ultra-fine spherical nano-particles of silver on few layers of graphene derived from highly oriented pyrolytic graphite in ultra-high vacuum were characterized using in situ scanning tunneling microscopy (STM) in conjunction with X-ray photoelectron spectroscopy. The energetics of the Ag clusters was determined by DFT simulations. The Ag clusters appeared spherical with size distribution averaging approximately 2 nm in diameter. STM revealed the preferred site for the position of the Ag atom in the C-benzene ring of graphene. Of the three sites, the C-C bridge, the C-hexagon hollow, and the direct top of the C atom, Ag prefers to stay on top of the C atom, contrary to expectation of the hexagon-close packing. Ab initio calculations confirm the lowest potential energy between Ag and the graphene structure to be at the exact site determined from STM imaging.