RESUMO
Chemical analysis was performed on sediment samples collected in two sampling sessions (July and October) from Podu Iloaiei Dam Lake, one of the most important water resources used for aquaculture in north-eastern Romania. The concentration of 15 trace elements (TEs), 8 refractory elements (REs), and 15 rare earth elements (REEs)-determined using inductively coupled plasma mass spectrometry-showed variability largely dependent of the sampling points and collection time. Manganese was the most abundant TE, V and Cr were the most abundant REs, while Ce was one of the most abundant REEs. The cerium negative anomaly and Gd positive anomaly were observed in the Chondrite-normalized distributions. In October, the Ce anomaly showed significant negative correlation with Mn, emphasizing the water body oxidation potential. The identified positive Gd anomaly was most likely associated with the use of Gd-chelating agents in magnetic resonance imaging in Iasi, the largest medical hub in north-eastern Romania. Principal component analysis extracted three factors explaining 96.0% of the observed variance, i.e., rock weathering, leaching from soil surface, contributions from urban stormwater and atmospheric deposition (50.9%), pedological contributions (23.7%), and mixed anthropogenic sources (e.g., traffic, waste discharge, agricultural activities; 21.4%). The evaluation of pollution indices highlighted low and moderate degrees of contamination for most of the elements and a considerable degree of contamination for Cd. Assigned Cd sources included fertilizers and pesticides used in the near agricultural areas or the high traffic road located near the lake. Since contamination of aquatic ecosystems with harmful elements is a human health concern, further monitoring of specific vectors in the food chain of the investigated dam lake will be of the utmost importance.
RESUMO
The present paper reports the first size-resolved element measurements in the PM2.5 fraction collected throughout 2016 in the Iasi urban area in north-eastern Romania. Concentrations of water-soluble elements (Ag, Al, As, B, Ba, Be, Bi, Cd, Co, Cu, Cr, Fe, Ga, Mg, Mn, Mo, Ni, Pb, Rb, Se, Sr, Te, Ti, U, V, Zn) were determined using inductively coupled plasma mass spectrometry. Several water-soluble heavy metals (Al, Fe, Zn, As, Cr, Pb) exhibit clear seasonal patterns with maxima over the cold season and minima over the warm season. Elements as Al, Fe, Mg, Zn, Ni, Mn, and Cu present the highest levels in the PM2.5 fraction, indicating significant contributions from soil-dust resuspension or brake lining and tires. Clear fine mode size-dependent distributions were observed for anthropogenic source-origin elements (Pb, Zn, Cd, V, etc.) due to an acidity-driven metals dissolution process. Positive matrix factorization, concentration weighted trajectory and bivariate polar plot analyses were applied to the entire PM2.5 database. Based on relative concentrations of various elements, five factors associated with specific sources were identified. The most important contributions to the total PM2.5 mass concentration (during the total period) come from secondary formation of the ammonium sulfate form (~44%) and from nitrate (~37%). Resuspended dust accounts for a contribution of about 16%, while biomass burning mixed with NaCl salt/sea-salt sources contribute as much as ~3%. Traffic and industrial sources seem to yield little contribution (<0.05%). An assessment investigation of non-carcinogenic and carcinogenic health risks revealed water-soluble arsenic and chromium (VI) as elements with the largest incremental carcinogenic risks. Both metals have traffic and industrial related sources and therefore it is believed that in the future, at the local/regional level, these sources should receive attention by implementing appropriate emission control measures.
