Effect of the Sintering Mechanism on the Crystallization Kinetics of Geopolymer-Based Ceramics.

This research aims to study the effects of the sintering mechanism on the crystallization kinetics when the geopolymer is sintered at different temperatures: 200 °C, 400 °C, 600 °C, 800 °C, 1000 °C, and 1200 °C for a 3 h soaking time with a heating rate of 5 °C/min. The geopolymer is made up of kaolin and sodium silicate as the precursor and an alkali activator, respectively. Characterization of the nepheline produced was carried out using XRF to observe the chemical composition of the geopolymer ceramics. The microstructures and the phase characterization were determined by using SEM and XRD, respectively. The SEM micrograph showed the microstructural development of the geopolymer ceramics as well as identifying reacted/unreacted regions, porosity, and cracks. The maximum flexural strength of 78.92 MPa was achieved by geopolymer sintered at 1200 °C while the minimum was at 200 °C; 7.18 MPa. The result indicates that the flexural strength increased alongside the increment in the sintering temperature of the geopolymer ceramics. This result is supported by the data from the SEM micrograph, where at the temperature of 1000 °C, the matrix structure of geopolymer-based ceramics starts to become dense with the appearance of pores.

Development and Characterization of Polylactic Acid (PLA)-Based Nanocomposites Used for Food Packaging.

The present study is focused on polylactic acid (PLA) blending with bio nanoadditives, such as Tonsil® (clay) and Aerosil®, to obtain nanocomposites for a new generation of food packaging. The basic composition was enhanced using Sorbitan oleate (E494) and Proviplast as plasticizers, increasing the composite samples' stability and their mechanical strength. Four mixtures were prepared: S1 with Tonsil®; S2 with Aerosil®; S3 with Aerosil® + Proviplast; and S4 with Sabosorb. They were complexly characterized by FT-IR spectroscopy, differential scanning calorimetry, mechanical tests on different temperatures, and absorption of the saline solution. FTIR shows a proper embedding of the filler component into the polymer matrix and DSC presents a good stability at the living body temperature for all prepared samples. Micro and nanostructural aspects were evidenced by SEM and AFM microscopy, revealing that S3 has the most compact and uniform filler distribution and S4 has the most irregular one. Thus, S3 evidenced the best diametral tensile strength and S4 evidenced the weakest values. All samples present the best bending strength at 18 °C and fair values at 4 °C, with the best values being obtained for the S1 sample and the worst for S4. The lack of mechanical strength of the S4 sample is compensated by its best resistance at liquid penetration, while S1 is more affected by the liquid infiltrations. Finally, results show that PLA composites are suitable for biodegradable and disposable food packages, and the desired properties could be achieved by proper adjustment of the filler proportions.

Effects of Multiple Reflow on the Formation of Primary Crystals in Sn-3.5Ag and Solder Joint Strength: Experimental and Finite Element Analysis.

The growth and formation of primary intermetallics formed in Sn-3.5Ag soldered on copper organic solderability preservative (Cu-OSP) and electroless nickel immersion gold (ENIG) surface finish after multiple reflows were systematically investigated. Real-time synchrotron imaging was used to investigate the microstructure, focusing on the in situ growth behavior of primary intermetallics during the solid-liquid-solid interactions. The high-speed shear test was conducted to observe the correlation of microstructure formation to the solder joint strength. Subsequently, the experimental results were correlated with the numerical Finite Element (FE) modeling using ANSYS software to investigate the effects of primary intermetallics on the reliability of solder joints. In the Sn-3.5Ag/Cu-OSP solder joint, the well-known Cu6Sn5 interfacial intermetallic compounds (IMCs) layer was observed in each reflow, where the thickness of the IMC layer increases with an increasing number of reflows due to the Cu diffusion from the substrate. Meanwhile, for the Sn-3.5Ag/ENIG solder joints, the Ni3Sn4 interfacial IMC layer was formed first, followed by the (Cu, Ni)6Sn5 IMC layer, where the formation was detected after five cycles of reflow. The results obtained from real-time imaging prove that the Ni layer from the ENIG surface finish possessed an effective barrier to suppress and control the Cu dissolution from the substrates, as there is no sizeable primary phase observed up to four cycles of reflow. Thus, this resulted in a thinner IMC layer and smaller primary intermetallics, producing a stronger solder joint for Sn-3.5Ag/ENIG even after the repeated reflow process relative to the Sn-3.5Ag/Cu-OSP joints.

Recent Developments in Steelmaking Industry and Potential Alkali Activated Based Steel Waste: A Comprehensive Review.

The steel industry is responsible for one-third of all global industrial CO2 emissions, putting pressure on the industry to shift forward towards more environmentally friendly production methods. The metallurgical industry is under enormous pressure to reduce CO2 emissions as a result of growing environmental concerns about global warming. The reduction in CO2 emissions is normally fulfilled by recycling steel waste into alkali-activated cement. Numerous types of steel waste have been produced via three main production routes, including blast furnace, electric arc furnace, and basic oxygen furnace. To date, all of the steel waste has been incorporated into alkali activation system to enhance the properties. This review focuses on the current developments over the last ten years in the steelmaking industry. This work also summarizes the utilization of steel waste for improving cement properties through an alkali activation system. Finally, this work presents some future research opportunities with regard to the potential of steel waste to be utilized as an alkali-activated material.

Selective Laser Sintering of PA 2200 for Hip Implant Applications: Finite Element Analysis, Process Optimization, Morphological and Mechanical Characterization.

Polyamide 12 (PA 22000) is a well-known material and one of the most biocompatible materials tested and used to manufacture customized medical implants by selective laser sintering technology. To optimize the implants, several research activities were considered, starting with the design and manufacture of test samples made of PA 2200 by selective laser sintering (SLS) technology, with different processing parameters and part orientations. The obtained samples were subjected to compression tests and later to SEM analyses of the fractured zones, in which we determined the microstructural properties of the analyzed samples. Finally, an evaluation of the surface roughness of the material and the possibility of improving the surface roughness of the realized parts using finite element analysis to determine the optimum contact pressure between the component made of PA 2200 by SLS and the component made of TiAl6V4 by SLM was performed.

Cast Iron Parts Obtained in Ceramic Molds Produced by Binder Jetting 3D Printing-Morphological and Mechanical Characterization.

Mechanical behavior and characteristics of two different types of materials: cast iron with lamellar graphite EN-GJL-250 and cast iron with spheroidal graphite EN-GJS-400-15 which were cast in ceramic molds using gravitational casting method has considered in this research. The ceramic molds were obtained by 3D printing method. First, a finite element analysis was developed to determine Tresca and von Mises stresses and the deformations of the ceramic molds under an applied pressure of 25 MPa. Samples were produced by gravitational casting using two types of cast iron materials. Mechanical tests were made using samples produced from these two types of materials and microstructure analysis evaluation of fractured zones was realized by scanning electron microscopy. Obtained results were finally used for designing, developing, and producing of one 'hydraulic block' of a railway installation by the Benninger Guss company of Switzerland.

Correction: Razvan et al. Selective Laser Sintering of PA 2200 for Hip Implant Applications: Finite Element Analysis, Process Optimization, Morphological and Mechanical Characterization. Materials2021, 14, 4240.

The authors wish to make the following correction to their paper [...].

Innovative Use of Sheep Wool for Obtaining Materials with Improved Sound-Absorbing Properties.

In recent years, natural materials are becoming a valid alternative to traditional sound absorbers due to reduced production costs and environmental protection. This study explores alternative usage of sheep wool as a construction material with improved sound absorbing properties beyond its traditional application as a sound absorber in textile industry or using of waste wool in the textile industry as a raw material. The aim of this study was to obtain materials with improved sound-absorbing properties using sheep wool as a raw material. Seven materials were obtained by hot pressing (60 ÷ 80 °C and 0.05 ÷ 6 MPa) of wool fibers and one by cold pressing. Results showed that by simply hot pressing the wool, a different product was obtained, which could be processed and easily manipulated. The obtained materials had very good sound absorption properties, with acoustic absorption coefficient values of over 0.7 for the frequency range of 800 ÷ 3150 Hz. The results prove that sheep wool has a comparable sound absorption performance to mineral wool or recycled polyurethane foam.