1.
Angew Chem Int Ed Engl
; 51(36): 9105-9, 2012 Sep 03.
Artigo
em Inglês
| MEDLINE
| ID: mdl-22855029
RESUMO
The metal-free amination of different aldehydes is catalyzed by hypoiodite, which is generated by employing commercially available sodium percarbonate as the co-oxidant. This approach has several advantages: it is a metal-free oxidation that works under mild reaction conditions; furthermore, it has a wide substrate scope and does not give toxic by-products from the co-oxidant that is used.