A 1-m non-resonant inelastic x-ray scattering spectrometer at BL15U, Shanghai Synchrotron Radiation Facility.

We report the design, construction, and commissioning of a spectrometer for non-resonant inelastic x-ray scattering study installed at BL15U, Shanghai Synchrotron Radiation Facility. It features a 1-m vertical scattering arm. An energy resolution of 1.3 eV is achieved based on the 1 m Rowland circle and the diced Si(555) crystal analyzer with a fixed Bragg angle of about 88.8°. The inelastic squared form factors of 21S + 21P of helium with respect to the momentum transfer were measured and compared with the accurate and reliable theoretical calculations in order to verify the spectrometer. Furthermore, the spectrometer is designed to work in the momentum transfer region of 0 Å-1 < q < 8.68 Å-1 and to initially focus on the non-resonant inelastic x-ray scattering studies on gaseous samples.

The realization of the dipole (γ, γ) method and its application to determine the absolute optical oscillator strengths of helium.

The dipole (γ, γ) method, which is the inelastic x-ray scattering operated at a negligibly small momentum transfer, is proposed and realized to determine the absolute optical oscillator strengths of the vanlence-shell excitations of atoms and molecules. Compared with the conventionally used photoabsorption method, this new method is free from the line saturation effect, which can seriously limit the accuracies of the measured photoabsorption cross sections for discrete transitions with narrow natural linewidths. Furthermore, the Bethe-Born conversion factor of the dipole (γ, γ) method varies much more slowly with the excitation energy than does that of the dipole (e, e) method. Absolute optical oscillator strengths for the excitations of 1s(2) → 1 snp(n = 3-7) of atomic helium have been determined using the high-resolution dipole (γ, γ) method, and the excellent agreement of the present measurements with both those measured by the dipole (e, e) method and the previous theoretical calculations indicates that the dipole (γ, γ) method is a powerful tool to measure the absolute optical oscillator strengths of the valence-shell excitations of atoms and molecules.

Investigation of Compton profiles of molecular methane and ethane.

The Compton profiles of methane and ethane molecules have been determined at an incident photon energy of 20 keV based on the third generation synchrotron radiation, and the statistical accuracy of 0.2% is achieved near pz = 0. The density functional theory with aug-cc-pVTZ basis set was used to calculate the Compton profiles of methane and ethane. The present experimental Compton profiles are in better agreement with the theoretical calculations in the whole pz region than the previous experimental results, which indicates that the present experimental Compton profiles are accurate enough to serve as the benchmark data for methane and ethane molecules.