1.
Acta Crystallogr Sect E Struct Rep Online
; 66(Pt 2): o409, 2010 Jan 20.
Artigo
em Inglês
| MEDLINE
| ID: mdl-21579828
RESUMO
The crystal structure of the title compound, C(11)H(18)O(6)S(2), was determined to investigate the effect of the eclipsed mesyl groups on the bond length of the vicinal quaternary C atoms. The two quaternary C atoms of the noradamantane skeleton and the two O atoms to which they are connected all located essentially in the same plane [maximum deviation 0.01â Å], resulting in an eclipsing conformation of the C-O bonds. The C-C bond of the quaternary C atoms is 1.597â (3)â Å is considerably longer than the other C-C bonds of the mol-ecule.