1.
Org Lett
; 25(19): 3522-3526, 2023 May 19.
Artigo
em Inglês
| MEDLINE
| ID: mdl-37158704
RESUMO
The deconstructive ring cleavage of cyclic thioethers is achieved through a Chan-Lam type process with boron compounds. The sequential hydroboration/ring cleavage process from alkynes offered a new route to the preparation of vinyl sulfides based on the developed conditions. Further exploration has demonstrated the versatility of nucleophiles, delivering various functionalized sulfides featuring linear frameworks.