Spin-orbit fluctuations in frustrated heavy-fermion metal LiV(2)O(4).

Spin fluctuations were studied over a wide momentum (ℏQ) and energy (E) space in the frustrated d-electron heavy-fermion metal LiV_{2}O_{4} by time-of-flight inelastic neutron scattering. We observed the overall Q-E evolutions near the characteristic Q=0.6 Å^{-1} peak and found another weak broad magnetic peak around 2.4 Å^{-1}. The data are described by a simple response function, a partially delocalized magnetic form factor, and antiferromagnetic short-range spatial correlations, indicating that heavy-fermion formation is attributable to spin-orbit fluctuations with orbital hybridization.

Superconductivity in an electron band just above the Fermi level: possible route to BCS-BEC superconductivity.

Conventional superconductivity follows Bardeen-Cooper-Schrieffer(BCS) theory of electrons-pairing in momentum-space, while superfluidity is the Bose-Einstein condensation(BEC) of atoms paired in real-space. These properties of solid metals and ultra-cold gases, respectively, are connected by the BCS-BEC crossover. Here we investigate the band dispersions in FeTe(0.6)Se(0.4)(Tc = 14.5 K ~ 1.2 meV) in an accessible range below and above the Fermi level(EF) using ultra-high resolution laser angle-resolved photoemission spectroscopy. We uncover an electron band lying just 0.7 meV (~8 K) above EF at the Γ-point, which shows a sharp superconducting coherence peak with gap formation below Tc. The estimated superconducting gap Δ and Fermi energy [Symbol: see text]F indicate composite superconductivity in an iron-based superconductor, consisting of strong-coupling BEC in the electron band and weak-coupling BCS-like superconductivity in the hole band. The study identifies the possible route to BCS-BEC superconductivity.

A-type antiferro-orbital ordering with I4(1)/a symmetry and geometrical frustration in the spinel vanadate MgV2O4.

We conduct a detailed structural analysis of the S=1 pyrochlore antiferromagnet MgV2O4, which exhibits an antiferromagnetic ordering marginally at TN=40 K, triggered by a structural transition from cubic to tetragonal symmetry at TS=62 K, using high resolution synchrotron x-ray diffraction and convergent beam electron diffraction. We reveal that the tetragonal phase below TS has the symmetry of I4(1)/a and that the distortion pattern of VO6 octahedra is consistent with A-type antiferro-orbital ordering with alternating stacking of layers with yz/xy orbital chains and zx/xy orbital chains along the tetragonal c axis. This implies that an anisotropic coupling of V moments produced by the orbital ordering below TS primarily brings about the antiferromagnetic ordering.

Evidence for a cos(4φ) modulation of the superconducting energy gap of optimally doped FeTe(0.6)Se(0.4) single crystals using laser angle-resolved photoemission spectroscopy.

We study the superconducting-gap anisotropy of the Γ-centered hole Fermi surface in optimally doped FeTe(0.6)Se(0.4) (T(c)=14.5 K), using laser-excited angle-resolved photoemission spectroscopy. We observe sharp superconducting (SC) coherence peaks at T=2.5 K. In contrast to earlier angle-resolved photoemission spectroscopy studies but consistent with thermodynamic results, the momentum dependence shows a cos(4φ) modulation of the SC-gap anisotropy. The observed SC-gap anisotropy strongly indicates that the pairing interaction is not a conventional phonon-mediated isotropic one. Instead, the results suggest the importance of second-nearest-neighbor electronic interactions between the iron sites in the framework of s(±)-wave superconductivity.

Unconventional s-wave superconductivity in Fe(Se,Te).

The superconducting state is characterized by a pairing of electrons with a superconducting gap on the Fermi surface. In iron-based superconductors, an unconventional pairing state has been argued for theoretically. We used scanning tunneling microscopy on Fe(Se,Te) single crystals to image the quasi-particle scattering interference patterns in the superconducting state. By applying a magnetic field to break the time-reversal symmetry, the relative sign of the superconducting gap can be determined from the magnetic-field dependence of quasi-particle scattering amplitudes. Our results indicate that the sign is reversed between the hole and the electron Fermi-surface pockets (s(+/-)-wave), favoring the unconventional pairing mechanism associated with spin fluctuations.

Anomalous metallic state in the vicinity of metal to valence-bond solid insulator transition in LiVS2.

We investigate LiVS2 and LiVSe2 with a triangular lattice as itinerant analogues of LiVO2 known for the formation of a valence-bond solid (VBS) state out of an S=1 frustrated magnet. LiVS2, which is located at the border between a metal and a correlated insulator, shows a first order transition from a paramagnetic metal to a VBS insulator at Tc approximately 305 K upon cooling. The presence of a VBS state in the close vicinity of insulator-metal transition may suggest the importance of itinerancy in the formation of a VBS state. We argue that the high temperature metallic phase of LiVS2 has a pseudogap, likely originating from the VBS fluctuation. LiVSe2 was found to be a paramagnetic metal down to 2 K.

Correlation-driven heavy-fermion formation in LiV2O4.

Optical reflectivity measurements were performed on a single crystal of the d-electron heavy-fermion (HF) metal LiV2O4. Our results evidence the highly incoherent charge dynamics above T* approximately 20 K and the redistribution of the spectral weight of the optical conductivity over broad energy scales ( approximately 5 eV) as the quantum coherence of the charge carriers is recovered. This reveals that LiV2O4 is close to a correlation-driven insulating state and indicates that, in sharp contrast to f-electron HF Kondo-lattice systems, strong electronic correlation effects dominate the heavy quasiparticle formation in LiV2O4.

Partially disordered antiferromagnetic phase in Ca(3)CoRhO(6).

Neutron diffraction experiments are reported on Ca(3)CoRhO(6) which consists of ferromagnetic Ising spin chains on a triangular lattice. It was first confirmed from temperature dependence of the (110) peak intensity that Ca(3)CoRhO(6) realizes a partially disordered antiferromagnetic state, where 2/3 of the ferromagnetic chains order antiferromagnetically with each other and the remaining 1/3 are left incoherent with the other chains. The 1/3 incoherent ferromagnetic Ising chains freeze to maintain a disordered state at lower temperatures. This compound is successfully discussed as a candidate of a nonequilibrium one-dimensional Ising model.