1.
Dalton Trans
; 47(25): 8476-8482, 2018 Jun 25.
Artigo
em Inglês
| MEDLINE
| ID: mdl-29901684
RESUMO
Several coordination polymers of silver(i)-pentacyanocyclopentadienide (PCC) were studied by X-ray diffraction to examine the effects of different solvents on supramolecular isomerism of the PCC-ligand. While alcohols yield supramolecular isomers of [Ag(PCC)] without coordination of solvent molecules, less polar solvents show coordinate binding. The influence of solvent polarity can be observed by a gradual change in the lattice structure featuring distinct motifs.