Mode Conversion Behavior of Guided Wave in a Pipe Inspection System Based on a Long Waveguide.

To make clear the mode conversion behavior of S0-mode lamb wave and SH0-plate wave converting to the longitudinal mode guided wave and torsional mode guided wave in a pipe, respectively, the experiments were performed based on a previous built pipe inspection system. The pipe was wound with an L-shaped plate or a T-shaped plate as the waveguide, and the S0-wave and SH0-wave were excited separately in the waveguide. To carry out the objective, a meander-line coil electromagnetic acoustic transducer (EMAT) for S0-wave and a periodic permanent magnet (PPM) EMAT for SH0-wave were developed and optimized. Then, several comparison experiments were conducted to compare the efficiency of mode conversion. Experimental results showed that the T(0,1) mode, L(0,1) mode, and L(0,2) mode guided waves can be successfully detected when converted from the S0-wave or SH0-wave with different shaped waveguides. It can also be inferred that the S0-wave has a better ability to convert to the T(0,1) mode, while the SH0-wave is easier to convert to the L(0,1) mode and L(0,2) mode, and the L-shaped waveguide has a better efficiency than T-shaped waveguide.

Photoreaction of rac-leucine in ice by circularly polarized synchrotron radiation: temperature-induced mechanism switching from Norrish Type†II to deamination.

The delivery of extraterrestrial organics to primitive Earth is considered to have triggered the origin and subsequent evolution of life. Indeed, enantiomerically enriched amino acids of nonterrestrial origin have been found in carbonaceous meteorites, and enantioselective photodecomposition by circularly polarized light (CPL) in outer space has been proposed to have played some role in the initial enantiomeric bias. To experimentally examine this possibility and elucidate the photoreaction mechanisms, we have studied the photolysis of racemic leucine (rac-Leu) in acidic and neutral ice/water media at 21-298 K with left- and right-CPL in an attempt to detect enantiomerically enriched D- and L-Leu, respectively. Comprehensive product analyses revealed that the CPL-induced deracemization of Leu proceeds in both acidic and neutral ice matrices even at 21 K, and that the main mechanism switches from Norrish-type II γ-hydrogen abstraction to SN i deamination on lowering the temperature. The potential role of the CPL-induced photodecomposition of amino acids as a source of the enantiomer imbalance in meteorites is discussed.

Simultaneous measurement of the phase and group velocities of Lamb waves in a laser-generation based imaging method.

This paper describes a novel approach to the simultaneous measurement of the phase and group velocities of Lamb waves based on images of their propagation. The laser-generation based imaging method was first introduced to obtain images of Lamb wave propagation. The time series of snapshot images is used to make a position-time diagram, and the velocities can be estimated based on the slopes of the position curves. Thus, the phase and group velocities can be obtained by measuring the phase advance and energy flow of the Lamb wave, respectively. Details of the principle of simultaneous measurement are presented herein. Experimental verification was also performed in the range of 0.2-3.0 MHz-mm using aluminum plates. The average errors between experiment and theory in the phase and group velocities were 3.31% and 5.68%, respectively.

Propagation phenomena of wideband guided waves in a bended pipe.

Ultrasonic guided waves in pipes have been anticipated as a rapid screening technique for pipe inspection because of their long-range propagation due to low energy leakage. In this paper, the propagation phenomena of guided waves in a bended pipe were investigated using a wideband laser ultrasonic system. The laser ultrasonic system, together with wavelet transformation, is a powerful tool for observing the dispersive phenomena intrinsic to guided waves. Bended stainless steel (SUS304) pipes with 6-mm outer diameter and 1-mm wall thickness were used in the experiments. The bending angles of the pipes were set to 0 degrees (straight pipe), 10 degrees, 30 degrees, 60 degrees and 90 degrees. The radius of the bend was 12.5 mm in all the pipes. A Q-switched Nd:YAG laser was employed to generate the guided waves. The generated guided waves were detected with a heterodyne interferometer. The obtained time-domain signals and their wavelet coefficients indicated the following two conclusions: (1) The amplitude of the F(1,1) mode converted from the L(0,1) mode increased with the increase of the bending angle. (2) Mode conversions from the L(0,1) to F(1,1) modes and vice versa were clearly observed in the low-frequency range up to around 200 kHz.

Enantioselective synthesis of near enantiopure compound by asymmetric autocatalysis triggered by asymmetric photolysis with circularly polarized light.

Right- and left-handed circularly polarized light (CPL) has been proposed as one of the origins of homochirality of biomolecules. However, the enantiomeric excess induced by CPL has been only very low (<2% ee). We found the unprecedented example of asymmetric autocatalysis triggered directly by a chiral physical factor, that is, right- and left-handed CPL, leading to a near enantiopure compound. Asymmetric photolysis of racemic pyrimidyl alkanol by r-CPL irradiation followed by asymmetric autocatalysis affords (R)-pyrimidyl alkanol with >99.5% ee. On the other hand, irradiation with l-CPL affords (S)-pyrimidyl alkanol with >99.5% ee. Thus, chiral physical power, such as CPL, in conjunction with asymmetric autocatalysis, provides a highly enantioenriched compound.

Absolute asymmetric photoreactions of aliphatic amino acids by circularly polarized synchrotron radiation: critically pH-dependent photobehavior.

The absolute asymmetric photoreaction (AAP) of racemic aliphatic amino acids, such as alanine (Ala) and leucine (Leu), by left- and right-handed circularly polarized light (l- and r-CPL) irradiation was investigated in aqueous solutions at various pHs, by using the Onuki-type polarizing undulator installed in an electron storage ring. The magnitude of the optical purity (op) generated and the enantiomer-enriching mechanism operative in the AAP were found to be entirely dependent on the ionic state (and thus pH) of the amino/carboxylic acid moieties. At pH 1, the op of Ala and Leu determined by circular dichroism (CD) spectral measurement gradually developed with CPL irradiation, according to Kagan's equation. In contrast, irradiation at pH 7 gave op's much smaller than the theoretical values predicted by Kagan's equation. However, it turned out that the photodecomposition at pH 7 produces the corresponding alpha-hydroxycarboxylic acids stereoselectively, the CD sign of which is just opposite to that of the remaining amino acid, thus affording the apparently small op. It is concluded that, irrespective of solution pH, the AAP of amino acid proceeds upon CPL irradiation. At pH 1, the photodecomposition of valine, Leu, and isoleucine occurs via a Norrish type II mechanism, which is also applicable to other amino acids possessing a gamma-hydrogen. In the case of amino acids lacking a gamma-hydrogen, such as glycine and Ala, the photodecomposition mechanism is a photodeamination/hydroxylation and a Norrish type I reaction. At pH 7, the main photoproducts were ammonia and alpha-hydroxycarboxylic acids that were produced via photodeamination.