3D N-doped carbon derived from zeolitic imidazole framework as heterogeneous catalysts for decomposition of pulp and paper mill effluent: Optimization and kinetics study.

Three specific catalysts, namely ZIF-67 (zeolitic imidazolate framework-67), Co@NCF (Co@Nitrogen-Doped Carbon Framework), and 3D NCF (Three-Dimensional Nitrogen-Doped Carbon Framework), were prepared and studied for pulp and paper mill effluent degradation using heterogeneous activation of peroxymonosulfate (PMS). Numerous characterizations, including scanning electron microscopy (SEM), X-ray diffraction (XRD), and N2 adsorption, were used to characterize the properties of three different catalysts. 3D NCF is remarkably effective at heterogeneous activation of PMS to generate sulfate radicals to degrade pulp and paper mill effluent (PPME) compared to the other as-prepared catalysts. The catalytic activity reveals a sequence of 3D NCF > Co@NCF > ZIF-67.3D NCF could degrade organic pollutants in 30 min at an initial COD concentration of 1146 mg/L of PPME, 0.2 g/L catalysts, 2 g/L PMS, and 50 °C. Consequently, it was observed that the degradation of PPME using 3D NCF followed first-order kinetics, with an activation energy of 40.54 kJ mol-1. Overall, 3D NCF/PMS system reveals promising performance for PPME removal.

Fabrication of hybrid covalent triazine framework-zinc ferrite spinel to uplift visible light-driven photocatalytic organic pollutant degradation.

The tunability of porous covalent triazine frameworks (CTFs) can mitigate poor photostability and rapid hole-electron recombination. Herein, an excellent improvement of visible light-driven photocatalytic pollutant degradation was achieved using a hybrid semiconductor of covalent triazine framework-zinc ferrite spinel catalysts (CTF-ZnFe2O4). The as-prepared CTF-ZnFe2O4 composites were fabricated using a facile one-pot ionothermal method. The hybrid photocatalysts were identified using X-ray diffraction (XRD), scanning electron microscopy/energy-dispersive X-ray (SEM-EDX), X-ray photoelectron spectrometer (XPS), Brunauer-Emmett-Teller (BET), Fourier transform infrared (FTIR), and UV-visible diffuse reflection spectroscopy (UV-vis DRS) characterizations. The analysis reveals that hybridization successfully ensued and altered the crystallinity structure, morphology, surface area, and bandgap energy of hybrid material. It was found that CTF-ZnFe2O4 90:10 is very effective for the degradation of MB in a UV-vis light photocatalytic process with the efficiency of 95.4% and kobs of 0.421 min-1 for degradation of 50 mg/L MB with 0.5 g/L dosages for 120 min. Additionally, the scavenger study, effect of additional oxidants, and stability were performed for the practical application of a hybrid photocatalyst. CTF-ZnFe2O4 90:10 shows outstanding pollutant degradation in sunlight irradiation and high stability with only a 5.2% reduction after a five-times sequential recycling process. Moreover, the photocatalytic mechanism of as-prepared CTF-ZnFe2O4 was mainly influenced by [Formula: see text] radical compared to [Formula: see text] and [Formula: see text] radicals. Overall, The as-prepared CTF-ZnFe2O4 shows significant potential to be utilized for photocatalytic wastewater treatment.

Synthesis of tungsten oxide/ amino-functionalized sugarcane bagasse derived-carbon quantum dots (WO3/N-CQDs) composites for methylene blue removal.

In this present study, the tungsten oxide/amino-functionalized sugarcane bagasse derived-carbon quantum dots (WO3/N-CQDs) composite has successfully been prepared through a simple mixing process. The WO3 was synthesized through a precipitation method, and CQDs were amino-functionalized using ethylenedinitrilotetraacetic acid (EDTA) and ethylenediamine (EDA) through one-pot hydrothermal method. It is revealed that N-CQDs incorporation into WO3 alters the bandgap energy, crystallinity, surface area, and photoluminescence (PL) properties. The produced composites exhibit higher monoclinic WO3 crystallinity, larger surface area, lower bandgap energy and quenched photoluminescence intensity. The as-prepared WO3/N-CQDs composites exhibit better adsorption and photocatalytic degradation performance of methylene blue (MB) than the pristine WO3. It shows that the combination of N-CQDs and WO3 enhanced visible light absorption, by lowering the bandgap energy of WO3 from 2.175 to 1.495 eV. The best performance composite is WO3/N-CQDs EDA 2.5% with an efficiency of 96.86%, removal rate constant of 0.02017/min, and chemical oxidation demand (COD) removal efficiency achieved 84.61%. Moreover, the WO3/N-CQDs EDA 2.5% shows a significant photocatalytic activity even at higher MB initial concentration with 92.93% removal for 50 ppm MB. Subsequently, the composite also has good stability after a sequential 3-times cycle of degradation with 86.85% removal. The increasing photocatalytic performance is affected by the quenching effect of PL and lower bandgap energy. The lower intensity of the PL indicates the reduced charge carrier recombination resulting in increased photocatalytic activity. The combination of N-CQDs and WO3 resulted in improved photodegradation, which shows its significant potential to be utilized for wastewater treatment.