1.
Chem Commun (Camb)
; 59(58): 8929-8932, 2023 Jul 18.
Artigo
em Inglês
| MEDLINE
| ID: mdl-37376915
RESUMO
Here we describe maturation of the [FeFe]-hydrogenase from its [4Fe-4S]-bound precursor state by using the synthetic complex [Fe2(µ-SH)2(CN)2(CO)4]2- together with HydF and components of the glycine cleavage system, but in the absence of the maturases HydE and HydG. This semisynthetic and fully-defined maturation provides new insights into the nature of H-cluster biosynthesis.