Films of filled single-wall carbon nanotubes as a new material for high-performance air-sustainable transparent conductive electrodes operating in a wide spectral range.

In this paper we show the advantages of transparent high conductive films based on filled single-wall carbon nanotubes. The nanotubes with internal channels filled with acceptor molecules (copper chloride or iodine) form networks demonstrating significantly improved characteristics. Due to the charge transfer between the nanotubes and filler, the doped-nanotube films exhibit a drop in electrical sheet resistance of an order of magnitude together with a noticeable increase of film transparency in the visible and near-infrared spectral range. The thermoelectric power measurements show a significant improvement of air-stability of the nanotube network in the course of the filling procedure. For the nanotube films with an initial transparency of 87% at 514 nm and electrical sheet resistance of 862 Ohm sq-1 we observed an improvement of transparency up to 91% and a decrease of sheet resistance down to 98 Ohm sq-1. The combination of the nanotube synthesis technique and molecules for encapsulation has been optimized for applications in optoelectronics.

Manifestation of plasmonic response in the detection of sub-terahertz radiation by graphene-based devices.

We report on the sub-terahertz (THz) (129-450 GHz) photoresponse of devices based on single layer graphene and graphene nanoribbons with asymmetric source and drain (vanadium and gold) contacts. Vanadium forms a barrier at the graphene interface, while gold forms an Ohmic contact. We find that at low temperatures (77 K) the detector responsivity rises with the increasing frequency of the incident sub-THz radiation. We interpret this result as a manifestation of a plasmonic effect in the devices with the relatively long plasmonic wavelengths. Graphene nanoribbon devices display a similar pattern, albeit with a lower responsivity.

Correction: Band gap modification and photoluminescence enhancement of graphene nanoribbon filled single-walled carbon nanotubes.

Correction for 'Band gap modification and photoluminescence enhancement of graphene nanoribbon filled single-walled carbon nanotubes' by A. I. Chernov et al., Nanoscale, 2018, DOI: 10.1039/c7nr07054c.

Band gap modification and photoluminescence enhancement of graphene nanoribbon filled single-walled carbon nanotubes.

Molecule encapsulation inside the single-walled carbon nanotube (SWCNT) core has been demonstrated to be a successful route for the modification of nanotube properties. SWCNT diameter-dependent filling results in band gap modification together with the enhancement of photoluminescence quantum yield. However, the interaction between the inner structure and the outer shell is complex. It depends on the orientation of the molecules inside, the geometry of the host nanotube and on several other mechanisms determining the resulting properties of the hybrid nanosystem. In this work we study the influence of encapsulated graphene nanoribbons on the optical properties of the host single-walled carbon nanotubes. The interplay of strain and dielectric screening caused by the internal environment of the nanotube affects its band gap. The photoluminescence of the filled nanotubes becomes enhanced when the graphene nanoribbons are polymerized inside the SWCNTs at low temperatures. We show a gradual photoluminescence quenching together with a selective signal enhancement for exact nanotube geometries, specifically (14,6) and (13,8) species. A precise adjustment of the optical properties and an enhancement of the photoluminescence quantum yield upon filling for nanotubes with specific diameters were assigned to optimal organization of the inner structures.

Hybrid mode-locked erbium-doped all-fiber soliton laser with a distributed polarizer.

A soliton-type erbium-doped all-fiber ring laser hybrid mode-locked with a co-action of arc-discharge single-walled carbon nanotubes (SWCNTs) and nonlinear polarization evolution (NPE) is demonstrated. For the first time, to the best of our knowledge, boron nitride-doped SWCNTs were used as a saturable absorber for passive mode-locking initiation. Moreover, the NPE was introduced through the implementation of the short-segment polarizing fiber. Owing to the NPE action in the laser cavity, significant pulse length shortening as well as pulse stability improvement were observed as compared with a SWCNTs-only mode-locked laser. The shortest achieved pulse width of near transform-limited solitons was 222 fs at the output average power of 9.1 mW and 45.5 MHz repetition frequency, corresponding to the 0.17 nJ pulse energy.

Thulium-doped mode-locked all-fiber laser based on NALM and carbon nanotube saturable absorber.

We present a thulium-doped fiber laser mode-locked by a carboxymetylcellulose high-optical quality film with dispersed single-walled carbon nanotubes. Laser system based on the nonlinear amplifying loop mirror generates the shortest pulses earlier obtained in SWCNT mode-locked thulium-doped fiber lasers with a duration of 450 fs and 18 mW maximum average power at 1870 nm.

Transform-limited pulse generation in normal cavity dispersion erbium doped single-walled carbon nanotubes mode-locked fiber ring laser.

We demonstrate an erbium doped fiber ring laser mode-locked with a carboxymetylcellulose high-optical quality film with dispersed single-walled carbon nanotubes (SWCNT). The laser with large normal net cavity dispersion generates near bandwidth-limited picosecond inverse modified soliton pulses at 1.56 µm.

Passive synchronization of all-fiber lasers through a common saturable absorber.

We present the synchronization of two all-fiber mode-locked lasers, operating at 1.0 µm and 1.54 µm, coupled through the use of a shared single-wall carbon nanotube absorber. Both lasers operate in the soliton-regime, achieving a synchronized repetition rate of 13.08 MHz. The broadband absorption range of the single-wall carbon nanotubes allows the stable mode-locking behavior at 1 µm and 1.5 µm. The nonlinear coupling effects between two energy states of the carbon nanotube absorber result in stable synchronized pulses for hours of operation, with a large cavity mismatch of 1400 µm.

Nonlinear coupling of relative intensity noise from pump to a fiber ring laser mode-locked with carbon nanotubes.

Pump relative intensity noise (RIN) has been recognized as a major source of noise in mode-locked lasers. The coupling of RIN from the pump to the output of a passively mode-locked fiber laser (PMFL) is systematically investigated using a pump modulation technique. It is found that the linear RIN coupling ratio from pump to PMFL is decreased with an increase in modulation frequency and is independent of modulation power. Moreover, the nonlinear RIN coupling from pump to PMFL is clearly demonstrated with a square wave modulated pump. The nonlinear RIN coupling ratio is noise power dependent. An exponential decay model based on the view of gain modulation is proposed and explains well the behavior of the nonlinear coupling phenomena.

Observation of timing jitter reduction induced by spectral filtering in a fiber laser mode locked with a carbon nanotube-based saturable absorber.

A self-starting passively mode-locked fiber laser with a carbon nanotube-based saturable absorber and a fiber-based bandpass filter (BPF) is proposed. Incorporation of a BPF into the cavity leads to a great reduction of its timing jitter from 84.8 to 29.1 fs (10 Hz-3 MHz). This happens because the filtering effect can weaken the fluctuation of the central wavelength induced by the quantum noise, being one of the important contributions to timing jitter in the optical amplifying process.

Timing-jitter reduction of passively mode-locked fiber laser with a carbon nanotube saturable absorber by optimization of cavity loss.

We investigate the relationship between timing jitter and cavity loss of a passively mode-locked fiber ring laser with a carbon nanotube as a saturable absorber. It is the first time that we experimentally demonstrated the reduction of timing jitter by properly increasing laser cavity loss. The lowest timing jitter is achieved when the cavity loss is optimized. Theoretical analysis is in agreement with the experimental observations on the effect of cavity loss for the reduction of timing jitter. Moreover, it is experimentally shown that, at an optimal value of cavity loss, the timing jitter is reduced significantly by 24%, while the relative intensity noise increased by 4% only.

Laser-based diagnostics applied to the study of BN nanotubes synthesis.

The boron nitride nanotubes (BNNTs) synthesis, using CO2-laser vaporization of a BN target under nitrogen gas, is investigated by UV-laser induced fluorescence (LIF) of the vapor phase and UV-Rayleigh scattering (RS) of the gas-suspended nanoparticles. The LIF signal from B atoms is mainly detected in the 1.5 mm-thick region above the BN target. It originates from a boron-rich vapor region confined near the hot boron droplet formed at the target surface. Then, recombination between hot boron and N2 gas occurs through a fast condensation process as revealed by both the depletion of B atoms from the vapor phase and the RS signal arising from the grown BN nanoparticles. Fluorescence spectra exhibit a strong peak at 250 nm due to boron fluorescence and mainly to nanoparticles Rayleigh scattering. A narrow peak is observed at 210 nm and a broader peak at 189 nm. These bands are tentatively assigned to fluorescence or photoluminescence (PL) from gaseous or solid BN species respectively since both gas and solid phases coexist in the plume due to the rapid cooling process. Two very weak bands occur at 308 nm and 350 nm. They are related to PL of defects bands from BN nanostructures on the basis of ex situ PL spectra of h-BN crystallites and multi-wall BNNTs. Detection of oxygen impurities is shown feasible through LIF from BO radical which is detected just above the BN target evaporated under vacuum pressure (approximately 1 mbar). An optical diagnostic strategy is demonstrated from these first in situ observations during BNNTs synthesis.