1.
Angew Chem Int Ed Engl
; 40(14): 2660-2662, 2001 Jul 16.
Artigo
em Inglês
| MEDLINE
| ID: mdl-11458364
2.
Angew Chem Int Ed Engl
; 40(14): 2660-2662, 2001 Jul 16.
Artigo
em Inglês
| MEDLINE
| ID: mdl-29712331
RESUMO
14π-Electrocyclization across the two pentafulvenoid moieties of pentafulvene 1 occurs upon heating to provide dicyclopenta[a,d]cyclooctene 2 [Eq. (1)]. The nonalternant hydrocarbon 2 shows diatropic character and a distinctive absorption spectrum with the longest wavelength maximum at 767 nm.