RESUMO
A cost-effective hexagonal sphericon hematite with predominant (110) facets for the oxygen evolution reaction (OER) is demonstrated. Sequential incorporation of near-atomic uniformly distributed Ce species and Ni nanoparticles into selected sites of the hematite induces a complex synergistic integration phenomenon that enhances the overall catalytic OER performance. This cheap hexagonal sphericon hematite (Fe ≈ 98%) only needs a small overpotential (η) of 0.34 V to reach 10 mA cm-2 , superior to commercial IrO2 and more expensive Co-, Ni-, and Li-based electrocatalysts.
RESUMO
We utilized a facile method for creating unique defects in the activated carbon (AC), which makes it highly active for the oxygen reduction reaction (ORR) and hydrogen evolution reaction (HER). The ORR activity of the defective AC (D-AC) is comparable to the commercial Pt/C in alkaline medium, and the D-AC also exhibits excellent HER activity in acidic solution.
RESUMO
Efficient yet inexpensive electrocatalysts for oxygen reduction reaction (ORR) are an essential component of renewable energy devices, such as fuel cells and metal-air batteries. We herein interleaved novel Co3O4 nanosheets with graphene to develop a first ever sheet-on-sheet heterostructured electrocatalyst for ORR, whose electrocatalytic activity outperformed the state-of-the-art commercial Pt/C with exceptional durability in alkaline solution. The composite demonstrates the highest activity of all the nonprecious metal electrocatalysts, such as those derived from Co3O4 nanoparticle/nitrogen-doped graphene hybrids and carbon nanotube/nanoparticle composites. Density functional theory (DFT) calculations indicated that the outstanding performance originated from the significant charge transfer from graphene to Co3O4 nanosheets promoting the electron transport through the whole structure. Theoretical calculations revealed that the enhanced stability can be ascribed to the strong interaction generated between both types of sheets.
RESUMO
We developed a novel approach to the fabrication of three-dimensional, nanoporous graphene sheets featuring a high specific surface area of 734.9 m(2) g(-1) and an ultrahigh pore volume of 4.1 cm(3) g(-1) through a rapid microwave-induced plasma treatment. The sheets were used as electrodes for supercapacitors and for the oxygen reduction reaction (ORR) for fuel cells. Argon-plasma grown sheets exhibited a 44% improvement of supercapacitive performance (203 F g(-1)) over the plasma grown sheets (141 F g(-1)). N-doped sheets with Co3O4 showed an outstanding ORR activity evidenced from the much smaller Tafel slope (42 mV/decade) than that of Pt/C (82 mV/decade), which is caused by the high electrical conductivity of the graphene sheets, the planar N species content and the nanoporous morphology.