Concentration and sources of persistent organic pollutants within the vicinity of a scrap-iron smelting plant: Seasonal pattern and health risk assessment.

Polychlorinated biphenyls (PCBs) are a class of ubiquitous and significant synthetic organic chemicals that pose deleterious threats to the environment and human health. This study examined the concentration, indoor-outdoor and seasonal change, sources, and health effects of PCBs in particulate-bound dust near a scrap iron recycling plant. PCBs levels were determined in samples using gas chromatograph mass spectrometer. The results indicated that 5 Cl atoms PCB constituted the majority of PCBs (41% overall), contributing 43% during the rainy season and 39% during the dry season. Dioxin-like PCBs (DLPCBs) contributed 38% during the rainy season and 33% during the dry season. In addition, DLPCB accounted for 26% and 40% of indoor and outdoor PCB emissions, respectively. Iron and steel production were identified as the highest identified contributing sources, accounting for 76% of PCB emissions in the rainy season, while plastic combustion had the highest contribution in the dry season, accounting for 44% of PCB emissions. Incremental Lifetime Cancer Risk assessment showed ingestion as the main exposure pathway for children and adults during the two seasons (74.42% and 58.24%, respectively), followed by dermal exposure, while inhalation had the least contribution. A multifaced approach involving relevant agencies, the industry, and the community is required to reduce exposure.

Quantifications and predictions of sectoral pollutants emissions in Nigeria from 1980 to 2050.

The fast-economic development and population growth in Nigeria have resulted in huge quantities of air pollutants emission which have implications on the environment. Detailed sectoral emission inventory to serve as the basis for policy formation to mitigate the condition is still lacking. This study builds detailed sectoral emission inventory using the emission factor approach to estimates various pollutant emissions from different sources. Five major sources of pollutant emissions were identified which include transportation, energy, municipal solid waste, wood fuel, and agricultural sectors. An increasing trend in emissions from 1980 to 2020 was observed for total emission of CO, NOx, PM2.5, PM10, SO2, NH3 and NMVOC in Nigeria that increased from 1 736-6 210; 143-338; 126-551; 171-717; 19-60; 4-28; and 471-1 587 Gg, respectively. Wood fuel, transportation, and municipal waste sectors are the major sources that contributed to 63%, 16%, and 15% of the total CO emission. Three mitigation scenarios for emission reduction for the future were analyzed. CO emission reductions of 38%, 24%, and 38% will be obtained from the liquefied petroleum gas (LPG) intervention, waste to energy (WTE) technology, and vehicle inspection and maintenance (VIM) policy scenarios, respectively, through to the year 2050.

Source identification and health risk assessments of heavy metals in indoor dusts of Ilorin, North central Nigeria.

Background and Purpose: Exposure to heavy metals (HMs) in indoor dusts is a serious public concern that is linked to a myriad of deleterious health outcomes. The objectives of this study are to estimate the contamination levels of HMs in indoor dusts of different residential areas in Ilorin, Nigeria; identify HMs sources in different residential areas; and evaluate human health risks of HMs in selected residential areas. Methods: Indoor dust sampling was conducted in ten randomly selected from low, medium and high population density residential areas of Ilorin, Nigeria. Ten HMs concentration levels, their health risk implication and the associated potential ecological risks were evaluated. Results: The mean concentration levels measured for Fe, Pb, Zn, As, Co, Cr, Cu, Cd, Mn and Ni were 38.99, 5.74, 3.99, 0.08, 2.82, 2.13, 0.47, 0.60, 6.45 and 1.09 mg/kg, respectively. Positive Matrix Factorization (PMF) model was applied to ascertain sources of HMs in sampled indoor dust. Percentage contribution from oil-based cooking (29.82%) and transportation (29.77%) represented the highest source to HM concentrations among the six factors identified. The results of the various pollution indices employed showed that Pb, Zn, As, Co, Cr, Cu, Mn and Ni contributed moderately to HMs concentration levels in the sampled dusts. Cd had highest potential ecological risk factor E r i of between 160 and 320. The average values of Enrichment Factors (EFs) obtained aside from Fe used as the reference metal, ranged between 8.46 (As) and 2521.61(Cd). Health risk assessment results revealed that children are the most susceptible to the risks associated with HMs bound indoor dust than the adults. The percentage risk contributions of Hazard Quotient via ingestion route (HQing) in Hazard Index (HI) for non-cancer risk of indoor HMs were 93.17% and 69.87% in children and adults, respectively. Likewise, the percentage cancer risks contribution through ingestion pathway (CRing) were higher than cancer risks through inhalation and dermal pathways (CRinh and CRdermal), accounting for 99.84% and 97.04% of lifetime cancer risk in children and adults, respectively. The contamination level of Cd recorded is of great concern and signifies very strong contribution from anthropogenic sources. Conclusion: This study has further revealed the levels of HMs in typical African residential settings that could be used by relevant stakeholders and policy makers in developing lasting control measures. Supplementary Information: The online version contains supplementary material available at 10.1007/s40201-021-00778-8.

Polycyclic aromatic hydrocarbons in road dusts of a densely populated African city: spatial and seasonal distribution, source, and risk assessment.

Road dust is a principal source and depository of polycyclic aromatic hydrocarbons (PAHs) in many urban areas of the world. Hence, this study probed the spatial and seasonal pattern, sources, and related cancer health risks of PAHs in the road dusts sampled at ten traffic intersection (TIs) of a model African city. Mixed PAHs sources were ascertained using the diagnostic ratios and positive matrix factorization (PMF) model. The results showed fluctuations in mean concentrations from 36.51 to 43.04 µg/g. Three-ring PAHs were the most abundant PAHs with anthracene (Anth) ranging from 6.84 ± 1.99 to 9.26 ± 4.42 µg/g being the predominant pollutant in Ibadan. Benzo(k)Fluoranthene (BkF) which is a pointer of traffic emission was the most dominant among the seven carcinogenic PAHs considered, varying from 2.68 ± 0.43 to 4.59 ± 0.48 µg/g. Seasonal variation results showed that PAH concentrations were 20% higher during dry season than rainy season. The seven sources of PAHs identified by PMF model include the following: diesel vehicle exhausts, gasoline combustion, diesel combustion, coal tar combustion, gasoline vehicle exhausts, coal and wood (biomass) combustion, and emissions from unburnt fossil fuels. Employing the incremental lifetime cancer risk (ILCR) model, the city's cancer risk of 5.96E-05 for children and 6.60E-05 for adults were more than the satisfactory risk baseline of ILCR ≤ 10-6 and higher in adults than in Children.

Source identification and health risk assessments of polycyclic aromatic hydrocarbons in settled dusts from different population density areas of Ilorin, Nigeria.

Polycyclic aromatic hydrocarbons (PAHs) have attracted significant attention in recent times on account of their reasonably high environmental burden and extreme toxicity. Samples of indoor dusts were obtained daily over a period of 2 weeks from 10 residences located within low, medium, and high density residential areas of Ilorin City. The concentration levels, potential sources, and cancer health risks of sixteen polycyclic aromatic hydrocarbons (PAHs) were investigated using gas chromatography/mass spectrometry. PAHs total concentrations varied from 3.95 ± 0.19 to 8.70 ± 0.43 µg/g with arithmetic mean of 6.09 ± 0.46 µg/g. Fluoranthene was the most dominant PAHs congener. High molecular weight (HMW) PAHs (4-6 rings) were the most prevalent PAHs and were responsible for 79.29% of total PAHs in sampled residences. Chrysene (Chry) was the most abundant compound among the 7 carcinogenic PAHs (CPAHs). Moreover, diagnostic ratios and positive matrix factorization (PMF) employed to apportion PAHs suggested that indoor dusts originated from indoor activities and infiltrating outdoor air pollutants. Diagnostic ratios revealed that PAHs are from mixed sources which include coal/wood combustion, non-traffic and traffic emissions, petroleum, petrogenic (gasoline), and petroleum combustion. Similarly, positive matrix factorization (PMF) model suggested five sources (factors) were responsible for PAHs in indoor dusts comprised of petroleum combustion and traffic emissions (60.05%), wood and biomass combustion emissions (20.84%), smoke from cooking, incense burning and tobacco (4.17%), gasoline combustion from non-traffic sources (13.89%), and emissions from coal burning and electronic devices (1.05%). The incremental lifetime carcinogenic risks (ILCR) of PAHs in adults and children estimated by applying benzo(a)pyrene (BaP) equivalent were within the satisfactory risk limits in Ilorin. Indoor PAHs emissions in Ilorin residences could be monitored and controlled by using data provided in this study.