Quantification and health impact assessment of polycyclic aromatic hydrocarbons (PAHs) emissions from crop residue combustion.

Emission of Polycyclic Aromatic Hydrocarbon compounds from combustion of crop residue was investigated. Crop residues comprising maize cobs, maize husks, rice husks and bean chaff were burnt in a furnace at a temperature of 400 °C and the emissions from the combustion process were characterized using standard methods. Health risk through inhalation was assessed using toxic equivalent factors and excess lifetime cancer risk. The results showed the detection of 16 PAH compound which included: Benzo[ghi]perylene, Naphthalene, Acenaphthene, Anthracene, Phenanthrene, Fluorene, Fluoranthene, Acenaphthylene, Pyrene, Benzo[a]anthracene, Dibenzo[a,h]anthracene, Benzo[b]fluoranthene, Chrysene, Benzo[a]pyrene, Indene[1,2,3-cd]pyrene and Benzo[k]fluoranthene. Benzo[b]fluoranthene had highest mean concentration of 1.30 µg/mg while Dibenzo[a,h]anthracene had the lowest mean concentration of 0.01 µg/mg. It was also revealed that the toxicity of PAHs was due to the presence of Benzo[b]fluoranthene for all the samples except for sample 4 for which the main contribution to toxicity was emission from benzo(a)pyrene, while the cancer risk assessment estimated to be 1.2 × 10-1 was far above the acceptable carcinogenic risk limit of 1 × 10-6. This study concluded that, more efforts are needed to reduce emission of PAHs from the combustion of crop residues into the ambient air otherwise, human health could be under threat especially if exposed for a long period.

Air emissions and health risk assessment around abattoir facility.

The study assessed the impacts of abattoir activities on ambient air quality and health risk associated with exposure to PM2.5 and PM10, H2S, SO2 and NH3. Air samplings were done simultaneously around the abattoir at three points for sixty consecutive days (October to November) and standard methods adopted for the samplings and analysis. Health risks associated with exposure to PM10 and PM2.5 were estimated, using attributable fractions, relative risk and the excess lifetime cancer risk. The non-carcinogenic risks induced by the inhalation of H2S, SO2 and NH3 were also evaluated using hazard quotient (HQ). The results indicated that the average concentrations of 18.75 µg/m3, 89.17 µg/m3 and 0.1ppm for PM2.5, PM10 and NO2 respectively, were higher than the World Health Organization (WHO), National Ambient Air Quality Standard (NAAQS) and Federal Ministry of Environment (FMEnv) permissible limits. Air Quality Index showed that the ambient air quality in respect of CO and NH3 was very good, moderate for PM10 and was very poor for NO2 and SO2. It was also shown that 0.32% of deaths from lung cancer, and 0.23% from cardiopulmonary could be avoided if PM2.5 is reduced to 3 µg/m3 and while about 0.14% of all-cause mortality could be avoided if PM10 is reduced to 10 µg/m3. In similar manner, at least 0.45% likelihood that an individual in a group of people exposed to PM2.5 100m away from the burning point may have health issue (lung cancer) than an individual from another set of people that is exposed to baseline concentration of 3 µg/m3. All the HQ values exceeded the threshold value, set at the unity, implying that H2S, SO2 and NH3 are likely to cause adverse health effects in the area. Conclusively, continuous operation of this abattoir within the residential area can constitute a great environmental menace to the residents of the area and can result in complication to those with existing health challenge.

Impact of elemental composition of particulate matter in the airshed of a University Farm on the local air quality.

The impact of particulate matter on the ambient air quality of Landmark University Farm was assessed using deposition fluxes of Trace elements (TEs) in the airshed of the farm. Deposition gauges were employed to collect both dry and wet deposition samples of particulate matter between 2018 and 2019. Elemental compositions of particulates collected during the sampling period were analyzed using Energy Dispersive X-ray Fluorescence Spectroscopy (ED-XRF). The deposition fluxes of crustal and anthropogenic trace elements were also determined using standard methods. Results showed that in dry season, iron has the highest mean concentration (3283.61 mg/kg), while chromium has the lowest (0.023 mg/kg). On the other hand, in wet season, silicon and nickel have the highest and lowest mean concentrations of 159.34 mg/kg and 0.01 mg/kg respectively. Although the concentrations of these metals were higher in the dry season than wet season, there was no statistical significant difference between the mean concentrations of the elements measured in each season of the year (p > 0.05). The compositions of some of the elements in the particulate matters were found to be far above the recommended exposure limits prescribed by OSHA. The study concluded that the elemental composition of particulate matter in the airshed of the University Farm adversely impacts the ambient air quality of the Community.