RESUMO
One-dimensional 27Al, 23Na Magic-Angle-Spinning (MAS) NMR and 27Al Multiple-Quantum Magic-Angle-Spinning NMR (MQMAS) measurements are reported for the δ-isomer of the Al13 Keggin structure at high spinning speed and 14.1 T field. Values for the CQ and η parameters are on the same scale as those seen in other isomers of the Al13 structure. Density functional theory (DFT) calculations are performed for comparison to the experimental fits using the B3PW91/6-31+G* and PBE0/6-31+G* levels of theory, with the Polarizable Continuum Model (PCM).
RESUMO
Rates of oxygen-isotope exchange were measured in the tetrasiliconiobate ion [H(2+x)Si(4)Nb(16)O(56)]((14-x)-) to better understand how large oxide ions interact with water. The molecule has 19 nonequivalent oxygen sites and is sufficiently complex to evaluate hypotheses derived from our previous work on smaller clusters. We want to examine the extent to which individual oxygen atoms react independently with particular attention given to the order of protonation of the various oxygen sites as the pH decreases from 13 to 6. As in our previous work, we find that the set of oxygen sites reacts at rates that vary over approximately 10(4) across the molecule at 6Assuntos
Química Orgânica/métodos
, Íons/química
, Isótopos de Oxigênio/química
, Oxigênio/química
, Cristalografia por Raios X
, Elétrons
, Concentração de Íons de Hidrogênio
, Cinética
, Espectroscopia de Ressonância Magnética
, Modelos Químicos
, Modelos Moleculares
, Nióbio/química
, Óxidos
, Oxigênio/metabolismo
, Isótopos de Oxigênio/metabolismo
, Prótons
, Silício/química
, Água/química