Recrystallization of water in non-water-soluble (meth)acrylate polymers is not rare and is not devitrification.

Change in the state of water sorbed into four kinds of non-water-soluble poly(meth)acrylates with low water content by temperature (T) perturbation was examined on the basis of T variable mid-infrared (MIR) spectroscopy. Many studies using differential scanning calorimetry suggested that there was no change in the state. T dependence of their MIR spectra, however, clearly demonstrated various changes in the state. Furthermore, recrystallization, which was crystallization during heating, was observed in all four polymers. The recrystallization observed in this study was not devitrification, which is the change in the state from glassy water to crystalline water, but vapor deposition during heating (vapor re-deposition). There were only two reports about recrystallization of water in a non-water-soluble polymer before this report; therefore, it might be considered to be a rare phenomenon. However, as demonstrated in this study, it is not a rare phenomenon. Recrystallization (vapor re-deposition) of water in the polymer matrices is related to a balance between flexibility and strength of the electrostatic interaction sites of polymer matrices but might not be related to the biocompatibility of polymers.

Thermally latent water in a polymer matrix.

Possible phase transition of water in polymer-water systems has been understood (assumed) to be only either freezing/melting or nothing, without relation to whether the polymer was soluble in water or whether its water content was high or low. This general understanding of water structure has been structured on the basis of calorimetric analyses such as differential scanning calorimetry, DSC. DSC is one of the most frequently used methods to analyze the water structure in polymer-water systems because the data obtained are relatively easy to interpret. This easiness of interpretation, however, can be accepted only if based on the understanding stated above. Unexpectedly, results of the infrared spectroscopic analysis presented here completely denied the general understanding and provided definite evidence of the existence of all phase transitions among the three states of water in a polymer solid. Furthermore, the impossibility of detection of condensation, deposition, sublimation, and vaporization by calorimetric analysis was revealed.