Photonic paper: Multiscale assembly of reflective cellulose sheets in Lunaria annua.

Bright, iridescent colors observed in nature are often caused by light interference within nanoscale periodic lattices, inspiring numerous strategies for coloration devoid of inorganic pigments. Here, we describe and characterize the septum of the Lunaria annua plant that generates large (multicentimeter), freestanding iridescent sheets, with distinctive silvery-white reflective appearance. This originates from the thin-film assembly of cellulose fibers in the cells of the septum that induce thin-film interference-like colors at the microscale, thus accounting for the structure's overall silvery-white reflectance at the macroscale. These cells further assemble into two thin layers, resulting in a mechanically robust, iridescent septum, which is also significantly light due to its high air porosity (>70%) arising from the cells' hollow-core structure. This combination of hierarchical structure comprising mechanical and optical function can inspire technological classes of devices and interfaces based on robust, light, and spectrally responsive natural substrates.

Silk Fibroin as Edible Coating for Perishable Food Preservation.

The regeneration of structural biopolymers into micelles or nanoparticles suspended in water has enabled the design of new materials with unique and compelling properties that can serve at the interface between the biotic and the abiotic worlds. In this study, we leveraged silk fibroin quintessential properties (i.e. polymorphism, conformability and hydrophobicity) to design a water-based protein suspension that self-assembles on the surface of food upon dip coating. The water-based post-processing control of the protein polymorphism enables the modulation of the diffusion of gases through the silk fibroin thin membranes (e.g. O2 and CO2 diffusion, water vapour permeability), which is a key parameter to manage food freshness. In particular, an increased beta-sheet content corresponds to a reduction in oxygen diffusion through silk fibroin thin films. By using the dip coating of strawberries and bananas as proof of principle, we have shown that the formation of micrometre-thin silk fibroin membranes around the fruits helps the management of postharvest physiology of the fruits. Thus, silk fibroin coatings enhance fruits' shelf life at room conditions by reducing cell respiration rate and water evaporation. The water-based processing and edible nature of silk fibroin makes this approach a promising alternative for food preservation with a naturally derived material.

Integration of silk protein in organic and light-emitting transistors.

We present the integration of a natural protein into electronic and optoelectronic devices by using silk fibroin as a thin film dielectric in an organic thin film field-effect transistor (OFET) ad an organic light emitting transistor device (OLET) structures. Both n- (perylene) and p-type (thiophene) silk-based OFETs are demonstrated. The measured electrical characteristics are in agreement with high-efficiency standard organic transistors, namely charge mobility of the order of 10(-2) cm(2)/Vs and on/off ratio of 10(4). The silk-based optolectronic element is an advanced unipolar n-type OLET that yields a light emission of 100nW.

Over 4000 nm bandwidth of mid-IR supercontinuum generation in sub-centimeter segments of highly nonlinear tellurite PCFs.

We report broad bandwidth, mid-IR supercontinuum generation using a sub-cm (8 mm) length of highly nonlinear tellurite microstructured photonic crystal fiber (PCF). We pump the fiber at telecommunication wavelengths by using 1550 nm, 100 fs pulses of energy E=1.9 nJ. When coupled in the PCF, these pulses result in a supercontinuum (SC) bandwidth of 4080 nm extending from 789 to 4870 nm measured at 20 dBm below the peak spectral power. This bandwidth is comparable or in excess of previously reported spectra for other nonlinear glass fiber formulations despite the significantly shorter fiber length. In addition, besides offering a convenient pump wavelength, short fiber lengths enable smoother SC spectra, lower dispersion, and reduced material absorption at longer wavelengths making the use of this PCF particularly interesting.

Initial dynamics of supercontinuum generation in highly nonlinear photonic crystal fiber.

We present a theoretical and experimental analysis of supercontinuum generation in very short lengths of high-nonlinearity photonic crystal fibers. The Raman response function for Schott SF6 glass is presented for what is believed to be the first time and used for numerical modeling of pulse propagation. Simulation and experiments are in excellent agreement and demonstrate the rapid transition to regimes of spectral complexity due to higher-order nonlinear effects.

High nonlinearity glass photonic crystal nanowires.

Soft glass photonic crystal fibers (PCFs) have been fabricated for the first time with the stack and draw process. The same SF6-PCFs have been successfully tapered using a brush flame method. The transverse structure of the PCF does not collapse in the tapering process and core dimensions of the fabricated photonic nanowire has been measured to be 400 nm in diameter. Supercontinuum radiation in excess of one octave has been generated in both the untapered and tapered PCF and, in the latter case, pulse energy thresholds of 65 picojoules at a pump wavelength of 1550 nm were observed.

Spectrally smooth supercontinuum from 350 nm to 3 mum in sub-centimeter lengths of soft-glass photonic crystal fibers.

The conversion of light fields in photonic crystal fibers (PCFs) capitalizes on the dramatic enhancement of several optical nonlinearities. We present here spectrally smooth, highly broadband supercontinuum radiation in a short piece of high-nonlinearity soft-glass PCF. This supercontinuum spans several optical octaves, with a spectral range extending from 350 nm to beyond 3000 nm. The selection of an appropriate propagation-length determines the spectral quality of the supercontinuum generated. Experimentally, we clearly identify two regimes of nonlinear pulse transformation: when the fiber length is much shorter than the dispersion length, soliton propagation is not important and a symmetric supercontinuum spectrum arises from almost pure self-phase modulation. For longer fiber lengths the supercontinuum is formed by the breakup of multiple Raman-shifting solitons. In both regions very broad supercontinuum radiation is produced.

Interaction of an optical soliton with a dispersive wave.

Scattering of a dispersive wave by optical solitons is studied experimentally in photonic crystal fibers in cases when the soliton and the dispersive wave have either identical or orthogonal polarization states. Observations of new resonant frequencies are reported. The experimental results are compared to numerical simulations and predictions from the recently derived wave vector matching conditions.

Time-spectrally-resolved ultrafast nonlinear dynamics in small-core photonic crystal fibers: Experiment and modelling.

Nonlinear dynamics of ultrashort optical pulses in the vicinity of the second zero-dispersion point of a small-core photonic crystal fiber is visualized and studied using cross-correlation frequency-resolved optical gating. New spectral features observed in the experiments match well with recent theoretical predictions of the generation of new frequencies via mixing of solitons and dispersive waves. Power- as well as length-dependent dynamics is obtained showing strong interaction between solitons and dispersive waves, soliton-soliton interaction, soliton stabilization against Raman self-frequency shift and Cherenkov continuum generation.

Transformation and control of ultra-short pulses in dispersion-engineered photonic crystal fibres.

Photonic crystal fibres (PCFs) offer greatly enhanced design freedom compared to standard optical fibres. For example, they allow precise control of the chromatic dispersion (CD) profile--the frequency dependence of propagation speed--over a broad wavelength range. This permits studies of nonlinear pulse propagation in previously inaccessible parameter regimes. Here we report on spectral broadening of 100-fs pulses in PCFs with anomalously flat CD profiles. Maps of the spectral and spatio-temporal behaviour as a function of power show that dramatic conversion (to both longer and shorter wavelengths) can occur in remarkably short lengths of fibre, depending on the magnitude and shape of the CD profile. Because the PCFs used are single-mode at all wavelengths, the light always emerges in a fundamental guided mode. Excellent agreement is obtained between the experimental results and numerical solutions of the nonlinear wave equation, indicating that the underlying processes can be reliably modelled. These results show how, through appropriate choice of CD, nonlinearities can be efficiently harnessed to generate laser light at new wavelengths.

Extruded soft glass photonic crystal fiber for ultrabroad supercontinuum generation.

We report the fabrication and properties of soft glass photonic crystal fibers (PCF's) for supercontinuum generation. The fibers have zero or anomalous group velocity dispersion at wavelengths around 1550 nm, and approximately an order of magnitude higher nonlinearity than attainable in comparable silica fibers. We demonstrate the generation of an ultrabroad supercontinuum spanning at least 350 nm to 2200 nm using a 1550 nm ultrafast pump source.

Adaptive control of femtosecond pulse propagation in optical fibers.

Nonlinear effects present fundamental obstacles to the propagation of femtosecond pulses of detectable energy in single-mode optical fibers, inducing severe distortion even after a very short (a few meters) propagation distance. We show here that adaptive pulse shaping can overcome these limitations by synthesizing pulses that are self-correcting for higher-order nonlinear effects when they are launched in the fiber. This approach would not only affect optical communications but also yield benefits in various disciplines requiring optimized fiber-based femtosecond pulse delivery, for example, nonlinear imaging techniques such as multiphoton microscopy, material processing, and medical diagnostics.

Simultaneous generation of spectrally distinct third harmonics in a photonic crystal fiber.

By coupling femtosecond pulses at lambda - 1.55mum in a short length (Z - 95 cm) of photonic crystal fiber, we observe the simultaneous generation of two visible radiation components. Frequency-resolved optical gating experiments combined with analysis and modal simulations suggest that the mechanism for their generation is third-harmonic conversion of the fundamental pulse and its split Raman self-shifted component.

Measurement of ultrafast ionization dynamics of gases by multipulse interferometric frequency-resolved optical gating.

Ultrafast ionization dynamics of femtosecond laser-irradiated noble and simple diatomic gases were studied using a novel two-color time-domain technique which eliminated significant complications seen in past experiments. Ultrafast depletion of the probing laser pulse was observed strictly coincident with the ionization front and attributed to a previously unobserved nonlinear frequency mixing via the transverse plasma current [F. Brunel, J. Opt. Soc. Am. B 7, 52 (1990)]. Good quantitative agreement of the measured single-atom ionization rates with Ammosov-Delone-Krainov rates was found, except for O (2) which showed a 200x smaller rate.

Convergence test for inversion of frequency-resolved optical gating spectrograms.

We describe a new and simple method to aid in the analysis of retrieved pulses from inverted frequency-resolved optical gating (FROG) traces. The analysis can separate noise from distortion and shows that distortion is more deleterious to the retrieved pulse than is pure noise. The analysis relies on the fact that FROG traces can be constructed from a single outer product of two vectors, whereas distortion and noise require the sum of a series of outer products.

Evolving FROGS: phase retrieval from frequency-resolved optical gating measurements by use of genetic algorithms.

We present a new technique based on genetic algorithms for retrieving the electric field and the phase of ultrashort pulses from frequency-resolved optical gating (FROG) traces. We have successfully applied a very basic genetic algorithm to the two most common beam geometries: polarization gate and second-harmonic generation (SHG). In the case of SHG FROG, the genetic algorithm returns a lower error than the standard iterative composite algorithm.

Observation of chirped soliton dynamics at lambda = 1.55 microm in a single-mode optical fiber with frequency-resolved optical gating.

We present an experimental observation of the dynamics of an initially chirped optical soliton at 1.55microm that is propagating through a single-mode optical fiber, using frequency-resolved optical gating (FROG). FROG permits observation of both the amplitude and the phase profiles of ultrashort pulses, providing complete information on the pulse evolution. The features that are detected, which include what is believed to be the first experimental observation of phase slips, are in quantitative agreement with numerical simulations that employ the nonlinear Schrödinger equation.

Full-field characterization of femtosecond pulses by spectrum and cross-correlation measurements.

We present a practical and accurate technique for retrieving the amplitude and the phase of ultrashort pulses from a nonlinear (second-order) intensity cross correlation and the spectrum that overcomes shortcomings of previous attempts. We apply the algorithm to theoretical and experimental data and compare it with frequency-resolved optical gating.

Second-harmonic generation frequency-resolved optical gating analysis of low-intensity shaped femtosecond pulses at 1.55 mum.

We illustrate observation and characterization of medium- and low-intensity shaped ultrashort pulses at lambda=1.55mum through single-shot geometry (multishot-average) second-harmonic generation-frequency-resolved optical gating. The pulses are shaped by amplitude filters in the Fourier plane of a compact folded shaper. Sensitivity to pulses with energies of less than 20 pJ and high dynamic range is reported for this configuration. Application of this method to the propagation of ~170-fs pulses through a 50-m fiber link is also illustrated.