RESUMO
The environmental and health risks of n-alkanes and benzene, toluene, ethylbenzene, and xylene (BTEX) in Eze-Iyi River at Isuikwuato oil spill site were evaluated. The water samples (60) were collected from upstream and downstream during the dry and rainy seasons. Concentrations of n-alkanes and BTEX were determined using a gas chromatograph coupled with a flame ionization detector. The percentage recovery of 87.3% and 92.0% was obtained for n-alkanes and BTEX in the water sample. The environmental risk analysis for n-alkanes and BTEX showed 80% of the water samples had a ratio greater than 1 indicating environmental risk in the area. Hydrocarbon source identification using biomarkers indicates that the n-alkane (nC16) dominant during the dry and rainy seasons was from anthropogenic/biogenic source, while nC14 and nC17 were from microbial and marine algae biogenic sources, respectively. The benzene levels in 100% (downstream) and 80% (upstream) of samples in the dry season and 40% (upstream) and 100% (downstream) of samples in the rainy season were above the WHO permissible limit of 0.01 mg/L for drinking water. The health risk index of n-alkanes during the dry season for children (upstream) was greater than 1 signifying adverse health risk. Therefore, consumption of water from the river should be discouraged and routine monitoring by regulatory authorities maintained to checkmate the build-up of BTEX and n-alkanes.
