RESUMO
The structural and catalytic properties of SiO2- and TiO2 -supported Pt-Au bimetallic catalysts prepared by coimpregnation were compared with those of samples of similar composition synthesized from a Pt2Au4(C{triple bond}CBut)8 cluster precursor. The smallest metal particles were formed when the bimetallic cluster was used as a precursor and TiO2 as the support. FTIR data indicate that highly dispersed Au crystallites in these samples, presumably located in close proximity to Pt, are capable of linearly coordinating CO molecules with a characteristic vibration observed at 2111 cm(-1). The cluster-derived Pt2Au4/TiO2 samples were the only ones exhibiting low-temperature CO oxidation activity, indicating that both the high dispersion of Au and the nature of the support are important factors affecting the catalytic activity for this system.
RESUMO
TiO2- and gamma-Al2O3-supported Pt catalysts were characterized by HRTEM, XPS, EXAFS, and in situ FTIR spectroscopy after activation at various conditions, and their catalytic properties were examined for the oxidation of CO in the absence and presence of H2 (PROX). When gamma-Al2O3 was used as the support, the catalytic, electronic, and structural properties of the Pt particles formed were not affected substantially by the pretreatment conditions. In contrast, the surface properties and catalytic activity of Pt/TiO2 were strongly influenced by the pretreatment conditions. In this case, an increase in the reduction temperature led to higher electron density on Pt, altering its chemisorptive properties, weakening the Pt-CO bonds, and increasing its activity for the oxidation of CO. The in situ FTIR data suggest that both the terminal and bridging CO species adsorbed on fully reduced Pt are active for this reaction. The high activity of Pt/TiO2 for the oxidation of CO can also be attributed to the ability of TiO2 to provide or stabilize highly reactive oxygen species at the metal-support interface. However, such species appear to be more reactive toward H2 than CO. Consequently, Pt/TiO2 shows substantially lower selectivities toward CO oxidation under PROX conditions than Pt/gamma-Al2O3.
