Functional Materials for Fabrication of Carbon-Based Perovskite Solar Cells: Ink Formulation and Its Effect on Solar Cell Performance.

Perovskite solar cells (PSCs) have rapidly developed into one of the most attractive photovoltaic technologies, exceeding power conversion efficiencies of 25% and as the most promising technology to complement silicon-based solar cells. Among different types of PSCs, carbon-based, hole-conductor-free PSCs (C-PSCs), in particular, are seen as a viable candidate for commercialization due to the high stability, ease of fabrication, and low cost. This review examines strategies to increase charge separation, extraction, and transport properties in C-PSCs to improve the power conversion efficiency. These strategies include the use of new or modified electron transport materials, hole transport layers, and carbon electrodes. Additionally, the working principles of various printing techniques for the fabrication of C-PSCs are presented, as well as the most remarkable results obtained from each technique for small-scale devices. Finally, the manufacture of perovskite solar modules using scalable deposition techniques is discussed.

A Critical Evaluation of the Influence of the Dark Exchange Current on the Performance of Dye-Sensitized Solar Cells.

The influence of the thickness of the nanostructured, mesoporous TiO2 film on several parameters determining the performance of a dye-sensitized solar cell is investigated both experimentally and theoretically. We pay special attention to the effect of the exchange current density in the dark, and we compare the values obtained by steady state measurements with values extracted from small perturbation techniques. We also evaluate the influence of exchange current density, the solar cell ideality factor, and the effective absorption coefficient of the cell on the optimal film thickness. The results show that the exchange current density in the dark is proportional to the TiO2 film thickness, however, the effective absorption coefficient is the parameter that ultimately defines the ideal thickness. We illustrate the importance of the exchange current density in the dark on the determination of the current-voltage characteristics and we show how an important improvement of the cell performance can be achieved by decreasing values of the total series resistance and the exchange current density in the dark.