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1.
Waste Manag ; 29(8): 2274-81, 2009 Aug.
Artigo em Inglês | MEDLINE | ID: mdl-19364641

RESUMO

Four methods for composting, pit-cover (PC), pit-open (PO), above ground-open (AO) and above ground-covered (AC), were compared for their effect in accelerating compost maturity using market crop waste (MCW). The composting process was monitored through determining changes in temperature and pH, with compost maturity indices measured in terms of variations in water-soluble carbon (WSC), ammonium-N (NH(4)(+)-N) and nitrate-N (NO(3)(-)-N), and C/N, NH(4)(+)-N/NO(3)(-)-N, WSC/organic N and WSC/total N (TN). Total organic carbon (TOC), nitrogen (TN), potassium (TK) and phosphorus (TP) were also determined. Temperature rapidly increased from mesophilic to thermophilic and gradually reduced through maturation phases. A similar pattern was recorded for pH, which reached a slightly alkaline level at maturity. Composting significantly (p<0.05) decreased the concentrations of TOC, TN, TP, TK, NH(4)(+)-N and WSC and increased that of NO(3)(-)-N. All four low-technology composting methods used in this study produced mature composts within 63 days. Suitable maturity indicators for MCW compost were C/N ratio<12, WSC<1%, NH(4)(+)-N<400 mg kg(-1), NH(4)(+)-N/NO(3)(-)-N<0.2, WSC/TN, WSC/organic-N<1. On the basis of these indicators, the AC method generally enhanced maturity faster than the AO, PC and PO methods. Pit methods require less investment and are recommended for the smallhold farmers.


Assuntos
Produtos Agrícolas , Recuperação e Remediação Ambiental/métodos , Eliminação de Resíduos/métodos , Solo/análise , Carbono/análise , Concentração de Íons de Hidrogênio , Nitrogênio/análise , Fósforo/análise , Compostos de Amônio Quaternário/análise , Temperatura , Fatores de Tempo
2.
Sci Total Environ ; 366(2-3): 749-59, 2006 Aug 01.
Artigo em Inglês | MEDLINE | ID: mdl-16309734

RESUMO

Metals occur naturally in soil, but contents are generally increased in the urban environment due to anthropogenic activities. The presence of elevated metals in soils of the urban environment has been recognized as an important source of metal intake in children and is linked to elevated metal levels in children's blood. Several metals have undesirable health effects, especially on children due to their still developing nervous system and small body volumes. Playgrounds are where urban children spend most of their time outdoors and are also where children most frequently come in contact with soil. Elevated contents of metals in playgrounds are therefore of great concern for children's wellbeing. This study investigates the soil metal content of 25 playgrounds located in different land use areas in urban Uppsala, Sweden's fourth largest city. Uppsala covers an area of approximately 100 km2 and has a population of 136,000. The soil samples were analysed for 12 metals (Al, As, Cd, Cr, Cu, Fe, Hg, Mn, Ni, Pb, W, Zn) using aqua regia. Median metal contents were found to be 1.8, 3.4, 0.21, 32, 25, 2.5, 0.14, 494, 19, 26, 0.35 and 84 mg kg(-1) soil for each of the above metals, respectively. The median clay content was around 20% while the organic matter content was measured by loss on ignition at a median of 8%. The land use areas included industrial land, the city center, road verges, natural land and former industrial land. The results showed that land use did not have the expected large influence on the total metal contents of the soils tested. The clay content together with the age of the site proved to be a more important factor. Sites with elevated clay contents had in general elevated metal contents, which were explained by the relatively high adsorption capacity of clay particles. The soils at sites where land use had not been altered since the 1800s had increased metal contents compared to playgrounds constructed in the late 1900s. The immobility of metals once they had entered the soil system was the reason for increased metal content in soils of old playgrounds. It was concluded that in cities with few internal pollution sources, the soil characteristics of the site and the time the soil has been on-site to accumulate metal residues become important factors in determining the soil metal content.


Assuntos
Metais/análise , Jogos e Brinquedos , Poluentes do Solo/análise , Arsênio/análise , Criança , Creches , Cidades , Monitoramento Ambiental , Humanos , Suécia
3.
J Environ Qual ; 33(1): 99-106, 2004.
Artigo em Inglês | MEDLINE | ID: mdl-14964363

RESUMO

The accumulation of P in agricultural soils due to fertilization has increased the risk of P losses from agricultural fields to surface waters. In risk assessment systems for P losses, both P release from soil to solution and transport mechanisms need to be considered. In this study, the overall objective was to identify soil variables for prediction of potential P release from soil to solution. Soils from nine sites of the Swedish long-term fertility experiment were used, each with four soil P levels. Phosphorus extractable with CaCl2 was used as an estimate of potential P release from soil to solution. Ammonium lactate-extractable phosphorus (P-AL) or NaHCO3-extractable phosphorus (Olsen P) could not be used alone for prediction of potential P release since soils with high phosphorus sorption capacity (PSC) released less P than soils with low PSC at the same soil test phosphorus (STP) level. Degree of phosphorus saturation (DPS) was calculated as Olsen P or P-AL as a percentage of PSC derived from P sorption isotherms or from Fe and Al extractable in ammonium oxalate. The CaCl2-extractable total phosphorus (CaCl2-TP) was exponentially related to these DPS values (r2 > or = 0.79). The CaCl2-TP was also linearly related to ratios between Olsen P or P-AL and a single-point phosphorus sorption index (PSI; r2 > or = 0.86). These ratios, which are easily determined and gave good correlations with CaCl2-TP, seemed to be the most useful estimates of potential P release for risk assessment systems.


Assuntos
Fósforo/química , Solo , Poluentes Químicos da Água , Poluição da Água/prevenção & controle , Fertilizantes , Humanos , Medição de Risco/métodos
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