RESUMO
NaCl islands are used as a sacrificial layer to selectively deposit a boronic acid based two-dimensional polymer. The nanostructured polymer layer can be used as a negative mask to create Fe islands in a nanolithography mimicking process.
Assuntos
Ácidos Borônicos/química , Nanoestruturas/química , Polímeros/química , Cloreto de Sódio/química , Ferro/química , Nanoestruturas/ultraestrutura , NanotecnologiaRESUMO
Control on the formation of a two-dimensional polymer could be achieved in two different ways. Manipulation with the tip of a scanning tunneling microscope allowed for assigning the localization of the polymerization reaction. Additionally, electron irradiation could accelerate greatly the reaction kinetics.
RESUMO
Supramolecular chemistry on a surface has produced a large variety of atomically controlled systems, but practical applications are seriously restricted by the use of weakly cohesive non-covalent bonds and by the confinement to a metal surface. Here we report on the formation of a well-ordered organometallic sheet consisting of two-dimensional polymeric phthalocyanine. Remarkably, the growth demonstrated on a metal surface can be extended onto a thin insulating film. We thus expect the intrinsic properties to be preserved, and the system should be easily transferable to real devices.
RESUMO
Alcohol oxidation and self-assembly: the in situ oxidation of hydroxyl functional groups to quinone groups promotes the formation of enhanced hydrogen bonds and allows reorganization of the resulting supramolecular self-assemblies, which evolve from a weakly bound dense phase to a strongly bound nanoporous open structure (see picture).