Achievement of over 1.4 V photovoltage in a dye-sensitized solar cell by the application of a silyl-anchor coumarin dye.

A dye-sensitized solar cell (DSSC) fabricated by using a novel silyl-anchor coumarin dye with alkyl-chain substitutes, a Br3-/Br- redox electrolyte solution containing water, and a Mg2+-doped anatase-TiO2 electrode with twofold surface modification by MgO and Al2O3 exhibited an open-circuit photovoltage over 1.4 V, demonstrating the possibility of DSSCs as practical photovoltaic devices.

Highly-efficient dye-sensitized solar cells with collaborative sensitization by silyl-anchor and carboxy-anchor dyes.

In dye-sensitized solar cells co-photosensitized with an alkoxysilyl-anchor dye ADEKA-1 and a carboxy-anchor organic dye LEG4, LEG4 was revealed to work collaboratively by enhancing the electron injection from the light-excited dyes to the TiO2 electrodes, and the cells exhibited a high conversion efficiency of over 14% under one sun illumination.

Fabrication of a high-performance dye-sensitized solar cell with 12.8% conversion efficiency using organic silyl-anchor dyes.

The co-sensitization of organic silyl-anchor dyes in dye-sensitized solar cells (DSSCs) using carbazole and coumarin dyes with organosilicon tethers for binding to titanium dioxide has been examined. We have succeeded in fabricating a high-performance DSSC with a light-to-electric energy conversion efficiency of 12.8% under one sun simulated solar irradiation.