1.
Phys Chem Chem Phys
; 17(14): 8638-41, 2015 Apr 14.
Artigo
em Inglês
| MEDLINE
| ID: mdl-25759865
RESUMO
A dinuclear copper(II) complex of 3,5-diamino-1,2,4-triazole is one of the highly active copper-based catalysts for the oxygen reduction reaction (ORR) in basic solutions. Our in situ X-ray absorption near edge structure measurements revealed that deprotonation of the triazole ligand might cause coordination geometrical changes, resulting in the enhancement of the ORR activity.