RESUMO
In this study, we developed an ink using hexanethiol and Cu(In,Ga)Se2 microcrystals (CIGSe MCs) to make thin films via doctor blade coating. Besides, crack-free thin films were obtained by optimizing CIGSe MC powder concentration and annealing temperature. Subsequently, single-step selenization was performed with and without sodium chloride (NaCl) surface treatment by carefully tuning the temperature. A crack-free surface with densely packed grains was obtained at 500 °C after NaCl treatment. Moreover, the structural parameters of the thin film (annealed at 350 °C) were significantly modified via selenization with NaCl at 500 °C. For instance, the FWHM of the prominent (112) plane reduced from 1.44° to 0.47°, the dislocation density minimized from 13.10 to 1.40 × 1015 lines per m2, and the microstrain decreased from 4.14 to 1.35 × 10-3. Remarkably, these thin films exhibited a high mobility of 26.7 cm2 V-1 s-1 and a low resistivity of 0.03 Ω cm. As a proof of concept, solar cells were engineered with a device structure of SLG/Mo/CIGSe/CdS/i-ZnO/Al-ZnO/Ag, wherein a power conversion efficiency (PCE) of 5.74% was achieved with exceptional reproducibility. Consequently, the outcomes of this investigation revealed the impact of selenization temperature and NaCl treatment on the physical properties and PCE of hexanethiol-based crack-free CIGSe MC ink-coated absorbers, providing new insights into the groundwork of cost-effective solar cells.
RESUMO
The efficient use of natural resources without negative repercussions to the environment has encouraged the incursion of nanotechnology to provide viable alternatives in diverse areas, including crop management. Agriculture faces challenges due to the combination of different abiotic stresses where nanotechnology can contribute with promising applications. In this context, several studies report that the application of nanoparticles and nanomaterials positively affects crop productivity through different strategies such as green synthesis of nanoparticles, plant targeted protection through the application of nanoherbicides and nanofungicides, precise and constant supply of nutrients through nanofertilizers, and tolerance to abiotic stress (e.g., low or high temperatures, drought, salinity, low or high light intensities, UV-B, metals in soil) by several mechanisms such as activation of the antioxidant enzyme system that alleviates oxidative stress. Thus, the present review focuses on the benefits of NPs against these type of stress and their possible action mechanisms derived from the interaction between nanoparticles and plants, and their potential application for improving agricultural practices.
