The Effect of Thermoplastic Elastomer and Fly Ash on the Properties of Polypropylene Composites with Long Glass Fibers.

A cost-effective solution to the problems that the automotive industry is facing nowadays regarding regulations on emissions and fuel efficiency is to achieve weight reduction of automobile parts. Glass fiber-reinforced polymers are regularly used to manufacture various components, and some parts may also contain thermoplastic elastomers for toughness improvement. This work aimed to investigate the effect of styrene-(ethylene-co-butylene)-styrene triblock copolymer (E) and treated fly ash (C) on the morphological, thermal, and mechanical properties of long glass fiber (G)-reinforced polypropylene (PP). Results showed that the composites obtained through melt processing methods presented similar thermal stability and improved (nano)mechanical properties compared to 25-30 wt.% G-reinforced PP composites (PP-25G/PP-30G). Specifically, the impact strength and surface hardness were greatly improved. The addition of 20 wt.% E led to a 25-39% increase in impact strength and surface elasticity, while the addition of 6.5 wt.% C led to a 16% increase in surface hardness. The composite based on 25 wt.% G, 6.5 wt.% C, and 20 wt.% E presented the best-balanced properties (8-17% increase in impact strength, 38-41% increase in axial strain, and 35% increase in surface hardness) compared with PP-30G/PP-25G. Structural and morphological analysis confirmed the presence of a strong interaction between the components that make the composites. Based on these results, the PP-G-E-C composites could be presented as a viable material for automotive applications.

Properties of Composites Based on Recycled Polypropylene and Silico-Aluminous Industrial Waste.

There is an ever-growing interest in recovering and recycling waste materials due to their hazardous nature to the environment and human health. Recently, especially since the beginning of the COVID-19 pandemic, disposable medical face masks have been a major source of pollution, hence the rise in studies being conducted on how to recover and recycle this waste. At the same time, fly ash, an aluminosilicate waste, is being repurposed in various studies. The general approach to recycling these materials is to process and transform them into novel composites with potential applications in various industries. This work aims to investigate the properties of composites based on silico-aluminous industrial waste (ashes) and recycled polypropylene from disposable medical face masks and to create usefulness for these materials. Polypropylene/ash composites were prepared through melt processing methods, and samples were analyzed to get a general overview of the properties of these composites. Results showed that the polypropylene recycled from face masks used together with silico-aluminous ash can be processed through industrial melt processing methods and that the addition of only 5 wt% ash with a particle size of less than 90 µm, increases the thermal stability and the stiffness of the polypropylene matrix while maintaining its mechanical strength. Further investigations are needed to find specific applications in some industrial fields.

Fungal Based Biopolymer Composites for Construction Materials.

Environmental contamination, extensive exploitation of fuel sources and accessibility of natural renewable resources represent the premises for the development of composite biomaterials. These materials have controlled properties, being obtained through processes operated in mild conditions with low costs, and contributing to the valorization of byproducts from agriculture and industry fields. A novel board composite including lignocelullosic substrate as wheat straws, fungal mycelium and polypropylene embedded with bacterial spores was developed and investigated in the present study. The bacterial spores embedded in polymer were found to be viable even after heat exposure, helping to increase the compatibility of polymer with hydrophilic microorganisms. Fungal based biopolymer composite was obtained after cultivation of Ganoderma lucidum macromycetes on a mixture including wheat straws and polypropylene embedded with spores from Bacillus amyloliquefaciens. Scanning electron microscopy (SEM) and light microscopy images showed the fungal mycelium covering the substrates with a dense network of filaments. The resulted biomaterial is safe, inert, renewable, natural, biodegradable and it can be molded in the desired shape. The fungal biocomposite presented similar compressive strength and improved thermal insulation capacity compared to polystyrene with high potential to be used as thermal insulation material for applications in construction sector.