Correlating soil nutrient test lead with bioaccessible lead in highly-contaminated soils receiving lead-immobilizing amendments.

Lead (Pb) is one of the most common metals exceeding human health risk guidelines for soil concentrations worldwide. Pb bioaccessibility is known to vary depending on soil physiochemical characteristics and, as a result, in vitro and in vivo tests exist that are used to estimate bioaccessible Pb in contaminated soils. Although in vitro tests such as the relative bioaccessibility leaching procedure (RBALP) present simpler and more cost-effective risk assessments than in vivo methods, soil tests such as Mehlich-3, Modified Morgan, and ammonium bicarbonate-diethylenetriamine pentaacetate (AB-DTPA) extractions are extremely routine and even more cost-effective. Currently, there are few comparisons examining the viability of common soil nutrient tests for assessing Pb bioaccessibility in soils from contaminated sites with extremely high total Pb concentrations or for sites that have received amendments, such as those containing compost, iron, and/or phosphorus, intended to immobilize Pb. Here, we examine the correlation between RBALP Pb and Pb as determined using three commonly utilized soil tests, Mehlich-3, Modified Morgan, and AB-DTPA, in archived samples from one Pb-contaminated site receiving compost amendment (Seattle, WA, USA) and one extremely Pb-contaminated site receiving mixtures of compost, P, and Fe (Joplin, MO, USA). At both the Seattle and Joplin sites separately, RBALP Pb was significantly correlated with all three soil nutrient test values, regardless of soil amendment. However, RBALP was only significantly correlated with Modified Morgan and total Pb when examining the Joplin and Seattle data together, likely resulting from different factors controlling Pb solubility at the two sites. These findings suggest that a diverse suite of relatively inexpensive and accessible soil nutrient test methods correlate with bioaccessible Pb at a specific site, regardless of whether Pb-immobilizing amendments have been used.

Influence of flow on phosphorus-dynamics and particle size in agricultural drainage ditch sediments.

Particle size is one factor affecting phosphorus (P) dynamics in soils and sediments. This study investigated how flow facilitated by hydraulic pumps and aquatic vegetation species water lettuce (Pistia stratiotes) and water hyacinth (Eichhornia crassipes) affected particle size and P-dynamics in organic sediments in agricultural drainage ditches. Sediments with finer particle size (>0.002 mm) were hypothesized to contain greater total P (TP) and less labile P than sediments with coarser particle size. Particle size was determined using a LS 13 320 Laser Diffraction Particle Size Analyzer. Sediments were tested for pH, TP, and organic matter. Fractions of P were determined using a sequential fractionation experiment and 31P Nuclear Magnetic Resonance (NMR) Spectroscopy. Larger average particle size and lower average total P concentrations were found in the inflows of the field ditches compared to the outflows. Presence of flow and aquatic vegetation did not have a significant impact on particle size, TP, or labile P fractions. Median (p = 0.10) particle size was not significantly correlated to TP. Overall, there was an average trend of coarser particle size and lower P concentrations in the inflow compared to the outflow. The presence of inorganic limerock could have affected results due to increased P adsorption capacity and larger average particle size compared to the organic fraction of the sediment.