A first-principles study on Ni-decorated MoS2 for efficient formaldehyde degradation over a wide temperature range.

The development of a high-efficiency, low-cost, and environmentally friendly catalyst for formaldehyde degradation is crucial for addressing the issue of indoor formaldehyde pollution. Given that modern individuals spend over 90% of their time indoors, effectively tackling indoor formaldehyde pollution holds significant importance. Therefore, this paper proposes an efficient catalyst for formaldehyde degradation: surface modification of MoS2 by single-atom Ni, which can convert formaldehyde into harmless H2O and CO2. The DFT method is employed to systematically investigate the oxidative degradation pathways of formaldehyde on the surface of Ni-doped MoS2. The research focuses on two common oxidative degradation pathways in both the L-H mechanism and E-R mechanism. Our findings demonstrate that these four reaction paths occur spontaneously within the temperature range of 300-800 K with a reaction equilibrium constant greater than 105. Moreover, even under extreme temperature conditions (100 K), the reaction rate remains favorable. Furthermore, our findings indicate that the minimum activation energy is merely 0.91 eV and H2O and CO2 only need to overcome an energy barrier of 0.71 eV for desorption from the catalyst surface. This substantiates its potential application both in indoor environments and under extreme temperature conditions. This theoretical research provides innovative ideas and strategies for effectively oxidizing formaldehyde.

Nonvolatile magnetoelectric coupling in two-dimensional van der Waals sandwich heterostructure CuInP2S6/MnCl3/CuInP2S6.

Electrical control of magnetism is of great interest for low-energy-consumption spintronic applications. Due to the recent experimental breakthrough in two-dimensional materials, with the absence of hanging bonds on the surface and strong tolerance for lattice mismatch, heterogeneous integration of different two-dimensional materials provides a new opportunity for coupling between different physical properties. Here, we report the realization of nonvolatile magnetoelectric coupling in vdW sandwich heterostructure CuInP2S6/MnCl3/CuInP2S6. Using first-principles calculations, we reveal that when interfacing with ferroelectric CuInP2S6, the Dirac half-metallic state of monolayer MnCl3 will be destroyed. Moreover, depending on the electrically polarized direction of CuInP2S6, MnCl3 can be a half-metal or a ferromagnetic semiconductor. We unveil that the obtained ferromagnetic semiconductor in MnCl3 can be attributed to the different gain and loss of electrons on the two adjacent Mn atoms due to the sublattice symmetry broken by interlayer coupling. The effects of interfacial magnetoelectric coupling on magnetic anisotropy and ferromagnetic Curie temperature of MnCl3 are also investigated, and a multiferroic memory based on this model is designed. Our work not only provides a promising way to design nonvolatile electrical control of magnetism but also renders monolayer MnCl3 an appealing platform for developing low-dimensional memory devices.

Tunable and switchable multi-wavelength pulsed fiber laser based on a nonlinear optical loop mirror and an improved Sagnac filter.

We propose and experimentally demonstrate a tunable and switchable multi-wavelength erbium-doped fiber ring pulsed laser based on a nonlinear optical loop mirror (NOLM) and an improved Sagnac filter. To achieve multi-wavelength pulsed laser output, we adopt a NOLM as a quasi-saturable absorber and an improved Sagnac loop as a wavelength selected filter. The constructed laser has a maximum output wavelength number of five with a pulse repetition frequency of 40.45 kHz and pulse duration of 108 ns. The laser can output single-wavelength and dual-wavelength pulsed lasers within a certain wavelength tuning range and a five-wavelength pulsed laser with a constant wavelength interval of 3 nm by adjusting the polarization controller. Dual-wavelength, three-wavelength, and four-wavelength pulsed lasers with various wavelength intervals are also obtained. The output performance of the constructed laser is tested with a maximum average output power of 127.45 µW and minimum pulse duration of 52 ns, and the stability of the laser output is also tested with a maximum power fluctuation of 0.62 dB and minimum wavelength drift of 0.51 nm with pump power of 350 mW.

Tunable and switchable multi-wavelength actively Q-switched random fiber laser based on an electro-optic modulator and Sagnac loop filter.

In this article, an actively Q-switched multi-wavelength random fiber laser based on a Sagnac loop filter and electro-optic modulator is proposed and demonstrated experimentally. The random distributed feedback media is a section of a 25 km long single-mode fiber. When the pump power is 350 mW, the polarization angle of the Sagnac loop filter can be adjusted by polarization controller to achieve the switching of a single, double, triple, and quadruple channels laser output. In the case of a single laser channel, dual laser channels, and three laser channels output, multiple laser channels can be tuned simultaneously with a fixed wavelength interval. In addition, by changing the waveform of the external signal source, the light and dark pulses can be switched. Owing to the half-open cavity structure and the high gain of the erbium-doped fiber, the laser threshold was reduced to 25 mW, and the light conversion efficiency was 0.67%. The laser is an ideal light source for medical imaging and long-distance sensing.

Bilayer hexagonal structure MnN2 nanosheets with room-temperature ferromagnetic half-metal behavior and a tunable electronic structure.

Two-dimensional (2D) layered materials have atomically thin thickness and outstanding physical properties, attracting intensive research in the past year. As one of these materials, a 2D magnet is an ideal platform for fundamental physics research and magnetic device development. Recently, a non-MoS2-type geometry was found to be more favorable in 2D transition-metal dinitrides. In this work, driven by this new configuration, we perform a comprehensive first-principles study on the bilayer hexagonal structure of 2D manganese dinitrides. Our results show that 2D MnN2 is a ferromagnetic half-metal at its ground state with 100% spin-polarization ratio at the Fermi energy level. The phonon spectrum calculation and ab initio molecular dynamics simulation show that the 2D MnN2 crystal has a high thermodynamic stability and its 2D lattice can be retained at room-temperature. Monte Carlo simulations based on the Heisenberg model predict a Curie temperature of over 563 K and its electronic properties can be regulated by biaxial strain. The half-metallic states are mainly contributed by Mn d orbitals, and the magnetic exchange of the system mainly comes from the Mn-N-Mn super-exchange. The p-d orbital hybridization will provide a small antiparallel magnetic moment of N atoms, and the p-orbital dangling bond can be eliminated by oxidation to enhance the total magnetic moment of the system. The study of magnetic anisotropy energy indicates that the easy magnetization axis is in-plane and hybridization between Mn dyz and dz2 orbitals gives the largest magnetic anisotropy contribution. In view of these results, we consider that novel 2D MnN2 is one of the most promising two-dimensional materials for nano-spintronic applications.

Replication-driven HBV cccDNA loss in chimeric mice with humanized livers.

Hepatitis B virus (HBV) infection is largely noncytopathic and requires the establishment of covalently closed circular DNA (cccDNA), which is considered stable in the nuclei of infected cells. Although challenging, approaches to directly target cccDNA molecules or kill infected cells are recommended to eliminate cccDNA. Herein, cccDNA levels were investigated in HBV-infected chimeric mice with humanized livers. HBV-infected cells support robust replication, progressively retain viral products, and head for cytopathic destruction and cccDNA loss. It is difficult for infected cells to retain cccDNA and remain noncytopathic. Replication-driven cccDNA loss is observed at both phases of spread of and persistent infection. The cccDNA replenishment is required to compensate for cccDNA loss. Blocking cccDNA replenishment pathways reduces cccDNA levels by >100-fold. These results prove an unconventional cccDNA elimination strategy that does not directly target cccDNA but aims to transform spontaneous cccDNA loss into progressive cccDNA elimination by blocking cccDNA replenishment.

Tunable and switchable multi-wavelength random distributed feedback fiber laser based on SMF and a cascaded Sagnac ring filter.

A tunable and switchable multi-wavelength random distributed feedback fiber laser based on cascaded Sagnac loops is proposed and experimentally demonstrated. The random distribution feedback of the laser is provided by the Rayleigh scattering generated by the single-mode fiber (SMF). The cascaded Sagnac loops act as a filter and a reflector in the half-open cavity laser. The single-, dual-, three-, and four-wavelength channels can be realized by adjusting the angle of the polarization controller at the pump power of 300 mW. In the single-, dual-, and three-wavelength channels, the wavelength spacing can be maintained, and the laser wavelength position can be changed at the same time. The maximum wavelength tuning ranges of single-, dual-, and three-wavelength outputs are about 4.5 nm, 2.6 nm, and 1 nm, respectively. The proposed multi-wavelength random fiber laser has the advantages of simple structure and low threshold, and it has good application prospects in remote sensing and imaging systems.

Free Vibration Analysis of a Graphene-Reinforced Porous Composite Plate with Different Boundary Conditions.

Plates are commonly used in many engineering disciplines, including aerospace. With the continuous improvement in the capacity of high value-added airplanes, large transport aircrafts, and fighter planes that have high strength, high toughness, and corrosion resistance have gradually become the development direction of airplane plate structure production and research. The strength and stability of metal plate structures can be improved by adding reinforced materials. This paper studies graphene platelets (GPLs) reinforced with a free vibration porous composite plate. The porous plate is constructed with a multi-layer model in a metal matrix containing uniform or non-uniformly distributed open-cell internal pores. Considering the random and directional arrangement of graphene platelets in the matrix, the elastic modulus of graphene composites was estimated using the Halpin-Tsai micromechanical model, and the vibration frequencies of graphene composite were calculated using the differential quadrature method. The effects of the total number of layers, GPL distribution pattern, porosity coefficient, GPL weight fraction, and boundary conditions on the free vibration frequency of GPLs reinforced porous composite plates are studied, and the accuracy of the conclusions are verified by the finite element software.

Mach-Zehnder fiber sensing and positioning system based on common optical path technology.

A Mach-Zehnder interferometer (MZI) fiber sensing and positioning system based on common optical path technology that combines the advantages of the positioning method of the conventional MZI and the common optical path technology is proposed to improve the performance of the system in this paper. The feasibility of the interferometer has been proved by simulation and experiment. In the conventional MZI, the temperature and environment have an effect on the system performance due to the interference light transmitted through different optical fibers. The system proposed in this paper overcomes the disadvantages of the conventional MZI.