Multifunctional integrated metamaterials for radar-infrared-visible compatible multispectral stealth.

Metamaterials offer exciting opportunities for developing multispectral stealth due to their unique electromagnetic properties. However, currently transparent radar-infrared-visible compatible stealth metamaterials typically involve complex hierarchical designs, leading to thickness and transparency limitations. Here, we propose an integrated metamaterial for multispectral stealth with high transparency. Our design features an ITO/dielectric/ITO sandwich structure, with the upper-layer ITO acting as a resonator for broadband microwave absorption while maintaining a high filling ratio to suppress infrared (IR) radiation. Experimental results demonstrate excellent performance, with over 90% microwave absorption in 8-18 GHz, an IR emissivity of approximately 0.36 in 3-14 µm, an average optical transmittance of 74.1% in 380-800 nm, and a thickness of only 2.4 mm. With its multispectral compatibility, the proposed metamaterial has potential applications in stealth and camouflage fields.

Metasurface Glass for Wireless Communication and Energy Saving.

With the growing global energy demand and environmental issues, energy saving technologies are becoming increasingly important in the building sector. Conventional windows lack energy saving and thermal insulation capabilities, while Low emissivity glass (Low-e glass) attenuates mobile communication signals while reflecting infrared. Therefore, this paper aims to design a type of windows for the "Sub 6GHz" frequency band of 5G. These windows combine the inherent transparency of traditional glass windows with the energy saving properties of Low-e glass, while also ensuring optimal communication performance within the 5G (Sub 6G) band. The metasurface glass is fabricated and subjected to simulation-guided experiments to evaluate their reliability and practicality. The metasurface glass is rigorously assessed in terms of microwave transmission performance, infrared low emissivity performance, and energy saving and thermal insulation capabilities.

Tunable Microwave Absorbing Devices Enabled by Reversible Metal Electrodeposition.

Tunable microwave absorbers have gained significant interest due to their capability to actively control microwaves. However, the existing architecture-change-based approach lacks flexibility, and the active-element-based approach is constrained by a narrowband operation or small dynamic modulation range. Here, a novel electrically tunable microwave absorbing device (TMAD) is demonstrated that can achieve dynamic tuning of the average reflection amplitude between -13.0 and -1.2 dB over a broadband range of 8-18 GHz enabled by reversible metal electrodeposition. This reversible tunability is achieved by electrodepositing silver (Ag) layers with controlled morphology on nanoscopic platinum (Pt) films in a device structure similar to a tunable Salisbury screen, employing Ag electrodeposited on Pt films as the modifiable resistive layer. Furthermore, this TMAD possesses a simple device architecture, excellent bistability, and multispectral compatibility. Our approach offers a new strategy for dynamically manipulating microwaves, which has potential utility in intelligent camouflage and communication systems.

Association Between Interleukin-6 Gene Polymorphism and Severity of Coronary Artery Disease in Patients with Diabetes.

Introduction: Previous studies have identified diabetes as a risk factor for coronary heart disease. This study determined the correlation between the IL-6 gene -572 G/C polymorphism and the incidence and severity of coronary heart disease in patients with diabetes. Methods: One hundred four patients with diabetes who were admitted to our hospital from January 2019 to December 2020 were retrospectively enrolled in the current study. These patients were divided into a diabetes only group (group A, 27 patients) and a diabetes complicated by coronary heart disease group (group B, 77 patients). Seventy patients in the latter group were further divided into low, medium, and high Syntax score groups based on coronary angiography results. A correlation analysis between IL-6, blood lipids, and the IL-6 -572 G/C gene levels was performed. Results: The serum IL-6 level in patients with the IL-6-572G/C-GG genotype was higher than patients with the GC and CC genotypes. In patients with diabetes, the presence of the IL-6-572G/C-GG and GC genotypes was associated with a significantly increased risk of developing coronary heart disease. Patients with the IL-6-572G/C-GG genotype and diabetes were shown to have more severe coronary artery lesions compared to patients with the CC genotype. Moreover, the G allele of the IL-6-572G/C gene was linked to a higher risk of coronary heart disease and more severe coronary artery lesions in patients with diabetes compared to the C allele. Conclusion: The IL-6-572G/C gene polymorphism is associated with the incidence and severity of coronary heart disease in patients with diabetes.

Transparent broadband absorber based on a multilayer ITO conductive film.

Present study reports a novel visible-light transparent, microwave broadband absorbing metamaterial. The designed structure is implemented using three different sizes of indium tin oxide (ITO) conductive film patch arrays, which is capable of achieving a reflection coefficient ≤ -10 dB from 2.2 to 18 GHz in simulations. Moreover, a fractional bandwidth of about 156.4% and the absorber thickness of only 0.088 times the cutoff wavelength (the lowest absorption frequency) was achieved. Changing the angle of incidence ensures a good absorption effect with large angle stability, and the absorber has good transmission in the visible range. In accordance with the simulation, a sample with a size of 299 × 299 mm was fabricated, and its wave absorption performance was assessed. The experimental results and the various incidence angles in the simulation of the TE and TM modes correspond well, allowing for the realization of large angle broadband absorption at frequencies ranging from 2.2 to 18 GHz. Thus, it has been found that the structure has good optical transparency and broadband radar absorption capability, both of which will have a wide range of applications in the fields of multi-spectrum stealth and electromagnetic compatibility.

Online analysis of chemical composition and size distribution of fresh cigarette smoke emitted from a heated tobacco product.

Online analysis of chemical composition of cigarette smoke of a heated tobacco product (HTP) was performed by using a home-made vacuum ultraviolet (VUV) lamp-based photoionization time-of-flight (TOF) mass spectrometer. A capillary inlet and an aerodynamic lens were utilized to sample the gas- and particulate-phase of the HTP smoke, without dilution and pretreatment, which can be switched from each other within minutes. A thermal desorption unit was installed to vaporize the particulate-phase into gas and its vaporization temperature was determined, based on an equilibrium between the evaporation efficiency and the thermal decomposition of organic compounds. Then these species were softly ionized by VUV photons and their ions were measured by a reflectron TOF mass analyzer. Meanwhile, the puff-by-puff resolved size distributions of the HTP smoke were probed with a commercial scanning mobility particle sizers (SMPS). The mean diameters of particles firstly increase with the puff number, mainly located in the range of 200 - 300 nm, and then approached a steady state. This method was validated to measure the physical-chemical characteristics of the HTP cigarette smoke.•A capillary inlet and an aerodynamic lens were utilized to sample the gas- and particulate-phase of the HTP smoke.•Chemical composition of the HTP smoke was measured by using a compact VUV photoionization mass spectrometer.•The particle size distribution of the HTP smoke without dilution was measured online.

Smart Metasurface for Active and Passive Cooperative Manipulation of Electromagnetic Waves.

Integrating active and passive manipulation of electromagnetic (EM) waves has significant advantages for the caliber synthesis of microwave and optical integrated devices. In previous schemes, most reported designs focus only on active ways of manipulating self-radiating EM waves, such as antennas and lasers, or passive ways of manipulating external incident EM waves, such as lenses and photonic crystals. Here, we proposed a paradigm that integrates active and passive manipulation of EM waves in a reconfigurable way. As demonstrated, circularly polarized, linearly polarized, and elliptically polarized waves with customized beams are achieved in passive operation by merging Pancharatnam-Berry phases and dynamic phases, while the radiating EM waves with a customized gain are achieved by coupling the coding elements with the radiation structure in the active manipulation. Either active or passive manipulation is determined by the sensed signals and operating state to reduce detectability. Encouragingly, the proposed strategy will excite new sensing and communication opportunities, enabling advanced conceptions for next-generation compact EM devices.

Digital Light Processing 3D-Printed Ceramic Metamaterials for Electromagnetic Wave Absorption.

Combining 3D printing with precursor-derived ceramic for fabricating electromagnetic (EM) wave-absorbing metamaterials has attracted great attention. This study presents a novel ultraviolet-curable polysiloxane precursor for digital light processing (DLP) 3D printing to fabricate ceramic parts with complex geometry, no cracks and linear shrinkage. Guiding with the principles of impedance matching, attenuation, and effective-medium theory, we design a cross-helix-array metamaterial model based on the complex permittivity constant of precursor-derived ceramics. The corresponding ceramic metamaterials can be successfully prepared by DLP printing and subsequent pyrolysis process, achieving a low reflection coefficient and a wide effective absorption bandwidth in the X-band even under high temperature. This is a general method that can be extended to other bands, which can be realized by merely adjusting the unit structure of metamaterials. This strategy provides a novel and effective avenue to achieve "target-design-fabricating" ceramic metamaterials, and it exposes the downstream applications of highly efficient and broad EM wave-absorbing materials and structures with great potential applications.

Time-resolved online analysis of the gas- and particulate-phase of cigarette smoke generated by a heated tobacco product using vacuum ultraviolet photoionization mass spectrometry.

We present a vacuum ultraviolet (VUV) lamp-based photoionization time-of-flight (TOF) mass spectrometer coupled with a capillary inlet and an aerodynamic lens to online analyze the chemical compositions of the gas- and particulate-phase of cigarette smoke of a heated tobacco product (HTP). Both phase compositions of the fresh cigarette smoke, without dilution and pretreatment, are softly photoionized and their mass spectra are measured with a time resolution of 1 s. It is shown that the gas-phase compositions with low mass are volatile organic compounds (VOCs), and the particulate-phase compositions are also clearly identified and cover the full mass range of the mass spectrometer. The time- or puff-by-puff resolved dynamic data are obtained for each species and provide abundant information to unravel the chemistry of the HTP smoke. In addition, the present results show that besides thermal vaporization, a couple of chemical reactions including pyrolysis and degradation have also occurred in the HTP smoking process, although its operation temperature is less than 350 °C. Even if not done here, this study paves the way to analyze the gas- and particulate-phase chemical compositions of a complex system in real time, like the cigarette smoke presented here, by using advanced soft ionization mass spectrometry.

Quasi-continuous linear phase-gradient metamaterial based on conformal spoof surface plasmon polaritons.

In this work, we propose a method of achieving quasi-continuous linear phase gradient for transmitted waves based on conformal spoof surface plasmon polariton (SSPP). To this end, a SSPP structure with high transmission is firstly designed as the unit cell of the metamaterial. To obtain the phase gradient, SSPP structures are arranged delicately in a way that they are conformal to the brachistochrone curve. In this way, quasi-continuous linear Pancharatnam-Berry (PB) phase profile can be realized strictly along one of the two transverse directions. To verify this idea, a dual-band transmissive metamaterial operating in X and Ku band was designed, fabricated and measured. Due to the phase gradient imparted by the conformal SSPP structures, high-efficiency anomalous refraction can be realized within the two bands. Different from the general PGM, the phase gradient of the conformal SSPP structure allows us to achieve the desired anomalous refraction angle without reconstructing the PB phase. Both the simulation and measurement results are well consistent with theoretical predictions. This work provides another strategy of achieving anomalous refraction and may find applications in beam steering, digital beam forming, etc.

Planar multi-angle retro-reflectors based on the wave-vector-reversion of spoof surface plasmon polaritons.

Spoof surface plasmon polariton (SSPP) is kind of sub-wavelength electromagnetic (EM) mode, which is favorable for miniaturization and thinning of EM devices. In this paper, we propose a method of designing thin planar retro-reflector that can operate under multiple incidence angles at the same frequency. The retro-reflector is composed of a transmissive phase gradient metasurface (TPGM) placed above a metallic patch array (MPA), where the former couples and decouples SSPPs while the latter supports eigen-mode propagation of SSPPs. Under oblique incident angles, the TGPM can impart 0 and π Pancharatnam-Berry (P-B) phases alternatively, producing P-B phase gradients along its surface. Incident waves can be coupled as SSPPs propagating on the MPA which will be reflected at the borders of the MPA, thus the wave-vector of SSPPs is reversed. In this way, retro-reflection can be realized under the two incidence angles θ=±45.0°. Moreover, due to mode mismatch between the TPGM and MPA under normal incidence, the retro-reflector acts like a planar metallic plate under θ=0°. To verify this method, a prototype was designed, fabricated and measured. Both the simulation and measurement results verify significant backscattering enhancement under θ=±45.0° and 0° at 10.0 GHz. This work provides an alternative method of designing planar retro-reflectors and may find applications in wireless communication, target tracking, etc.

Overcome chromatism of metasurface via Greedy Algorithm empowered by self-organizing map neural network.

Chromatism generally exists in most metasurfaces. Because of this, the deflected angle of metasurface reflectors usually varies with frequency. This inevitably hinders wide applications of metasurfaces to broadband signal scenarios. Therefore, it is of great significance to overcome chromatism of metasurfaces. With this aim, we firstly analyze necessary conditions for achromatic metasurface deflectors (AMD) and deduce the ideal dispersions of meta-atoms. Then, we establish a Self-Organizing Map (SOM) Neural Network as a prepositive model to obtain a diversified searching map, which is then applied to Greedy Algorithm to search meta-atoms with the required dispersions. Using these meta-atoms, an AMD was designed and simulated, with a thickness about 1/15 the central wavelength. A prototype was fabricated and measured. Both the simulation and measurement show that the proposed AMD can achieve an almost constant deflected angle of 22° under normal incidence within 9.5-10.5GHz. This method may find wide applications in designing functional metasurfaces for satellite communications, mobile wireless communications and others.

Trifunctional metasurface based on spoof surface plasmon polaritons.

In this paper, we propose the design of a metasurface that can achieve three functions in different frequency bands. The proposed metasurface is composed of two kinds of unit cells which are designed on the basis of the spatial k-dispersion engineering of spoof surface plasmon polaritons (SSPPs). By arranging these two kinds of unit cells in the chessboard configuration, the three functions of transmission, anomalous refraction and absorption can be integrated into one metasurface. High transmission and strong absorption can be achieved in 2.0-9.0 GHz and 12.6-20.0 GHz, respectively. Meanwhile, anomalous refraction can be achieved in 10-11.7 GHz due to forward scattering cancellation of two unit cells. To verify the design, a prototype was fabricated and measured. The measured results are consistent with the simulation ones. The metasurface can integrate multiple functions into one aperture and therefore has potential application values in multifunctional microwave devices such as shared-aperture antennas, etc.

An ultra-broadband terahertz metamaterial coherent absorber using multilayer electric ring resonator structures based on anti-reflection coating.

We propose a method for achieving THz ultra-broadband coherent absorption using the anti-reflection theory of metamaterials. The metamaterial absorber consists of a periodic array of electric ring resonators with a multilayered structure which form the desired refractive index dispersion and provide continuous anti-reflection over a wide frequency range. The destructive interference mechanism and resonance absorption of the absorber are determined by simulation analysis and numerical simulation. Simulation results show that the absorption bandwidth is almost 8.02 THz (absorption rate >90%) over the entire terahertz band (0.1 THz-10 THz). This design provides an effective and viable method for constructing broadband absorbers for stealth technology and the construction of enhanced transmittance devices.

Magnetic solid-phase extraction of tobacco-specific N-nitrosamines using magnetic graphene composite as sorbent.

Tobacco-specific N-nitrosamines are carcinogenic components in mainstream cigarette smoke. To explore tobacco-specific N-nitrosamine release levels in cigarettes, a magnetic solid-phase extraction procedure using magnetic graphene composite as sorbent for fast enrichment of tobacco-specific N-nitrosamine was developed. Under optimal conditions, a tobacco-specific N-nitrosamine determination method was successfully proposed by combining magnetic solid-phase extraction procedure and high-performance liquid chromatography coupled with tandem mass spectrometry. The method's limit of detection for tobacco-specific N-nitrosamines in mainstream cigarette smoke ranged from 0.018 to 0.057 ng/cigarette. Good linearities were obtained with correlation coefficients above 0.9992. The accuracies of tobacco-specific N-nitrosamines in a spiked mainstream cigarette smoke sample were from 89.3 to 109.4%, with a relative standard deviation of less than 11.2%. The proposed method has the merits of rapidity and high sensitivity. Finally, the method was successfully applied to tobacco-specific N-nitrosamine analysis in real samples.

Chemical Analysis and Simulated Pyrolysis of Tobacco Heating System 2.2 Compared to Conventional Cigarettes.

Introduction: Tobacco Heating System 2.2 (THS 2.2, marketed as iQOS) is a heat-not-burn (HNB) tobacco product that has been successfully introduced to global markets. Despite its expanding market, few independent and systematic researches into THS 2.2 have been carried out to date. Methods: We tested a comprehensive list of total particulate matter (TPM), water, tar, nicotine, propylene glycol, glycerin, carbon monoxide, volatile organic compounds, aromatic amines, hydrogen cyanide, ammonia, N-nitrosamines, phenol, and polycyclic aromatic hydrocarbon under both ISO and HCI regimes. We also simulated pyrolysis of THS 2.2 heating sticks and made comparisons with conventional cigarette tobacco fillers using comprehensive gas chromatography-mass spectrometry (GC × GC-MS) to determine whether the specially designed ingredients help reduce harmful constituents. Results: Other than some carbonyls, ammonia, and N-nitrosoanabasine (NAB), the delivered releases from THS 2.2 were at least 80% lower than those from 3R4F. Tar and nicotine remained almost the same as 3R4F. Interestingly, the normalized yield of THS 2.2 to 3R4F under the HCI regime was lower than that under the ISO regime. Conclusions: THS 2.2 delivered fewer harmful constituents than the conventional cigarette 3R4F. Simulated pyrolysis results showed that the lower temperature instead of specially designed ingredients contributed to the distinct shift. In particular, if smoking machines are involved to evaluate the HNB products, smoking regimes of heat-not-burn tobacco products should be carefully chosen. Implications: To our knowledge, few independent studies of HNB products have been published. In this paper, a comprehensive list of chemical releases was tested systematically and compared to those from 3R4F. Although THS 2.2 generates lower levels of harmful constituents, the nicotine and tar levels were almost identical to 3R4F.The results should be discussed carefully in the future when assessing the dual-use with other conventional cigarettes, nicotine dependence of HNB products, etc. This study also suggests that regulatory agencies should pay attention to the smoking regimes that are adopted to evaluate HNB tobacco products.

Transparent and broadband absorption-diffusion-integrated low-scattering metamaterial by standing-up lattice.

In this paper, a transparent absorption-diffusion-integrated metamaterial (ADMM) based on standing-up lattice structure is proposed which takes full advantage of electromagnetic absorption and destructive interference simultaneously for the suppression of broadband backward scattering within a wide angular domain, especially for the lower-frequency scattering. The proposed ADMM is constituted by two kinds of rhombic and squared ITO lattices arranged in a pseudorandom distribution and then backed with ITO film. Calculation, simulation, and experimental measurement show that the proposed ADMM can achieve low scattering with normalized reflection less than 0.1 in the frequency band of 6.1-21.0GHz. In addition, owing to the standing-up lattice structure, the averaged optical transmittance of our ADMM reaches the optimal value of around 82.1% in the visible wavelength range of 380-780nm, promising an excellent optical transparency. The proposed comprehensive scheme provides an effective way to achieve broadband scattering suppression and high compatibility with optical transparency, enabling a wide range of applications in the window glass of stealth armament, electromagnetic compatibility facility and photovoltaic solar device.

Transparent broadband metamaterial absorber enhanced by water-substrate incorporation.

In this paper, a transparent metamaterial absorber (MA) loaded with water substrate is presented, which can simultaneously achieve enhanced broadband microwave absorption and tunable infrared radiation. As a proof, the indium tin oxide (ITO) films are first introduced here as a frequency selective surface (FSS) on the top layer and reflective backplane on the ground layer. Next the distilled water combined with the polymethyl methacrylate (PMMA) substrate is employed as a hybrid substrate in the middle. Simulation and experimental measurements show that the transparent water-substrate MA can achieve broadband microwave absorption with efficiency over 90% in the frequency band of 6.4-23.7GHz, and the proposed hybrid substrate has almost no influence on its original transmittance. Moreover, owing to the available water circulation system, the infrared radiation of the proposed MA is also demonstrated to be controlled by the temperature of the injected water. Based on its multifunction and high performance, it is expected that the proposed design may find potential applications, such as glass window of stealth equipment, electromagnetic compatible buildings/facilities, etc.

Enantiomeric composition of nicotine in tobacco leaf, cigarette, smokeless tobacco, and e-liquid by normal phase high-performance liquid chromatography.

Evaluating the source of nicotine in e-liquid is a problem. Tobacco-derived nicotine contains predominantly (S)-(-)-nicotine, whereas tobacco-free nicotine products may not. Thus, we developed a new normal phase high-performance liquid chromatography method to determinate the enantiomeric composition of nicotine in 10 kinds of flue-cured tobacco, 3 kinds of burley, 1 kind of cigar tobacco, 2 kinds of oriental tobacco, 5 kinds of Virginia cigarette, 5 kinds of blend cigarette, 10 kinds of e-liquid, and 4 kinds of smokeless tobacco. The amount of (R)-(+)-nicotine ranged from ~0.02% to ~0.76% of total nicotine. An e-liquid sample had the highest level of (R)-(+)-nicotine. The extraction and purification processes used to obtain commercial (S)-(-)-nicotine from the tobacco do not decrease the amount of (R)-(+)-nicotine in tobacco. So the amount of (R)-(+)-nicotine in samples in our work were the same as tobacco samples.

Hybrid metasurfaces for microwave reflection and infrared emission reduction.

Controlling of electromagnetic wave radiation is of great importance in many fields. In this work, a hybrid metasurface (HMS) is designed to simultaneously reduce the microwave reflection and the infrared emission. The HMS is composed of the metal/dielectric/metal/dielectric/metal configuration. The reflection reduction at microwave frequencies mainly results from the phase cancellation technique, while the infrared emission reduction is due to the reflection of the metal with a high filling ration in the top layer. It has been analytically indicated that reflection reduction with an efficiency larger than 10 dB can be achieved in the frequency band of 8.2-18 GHz, and this has been well verified by the simulated and experimental results. Meanwhile, the designed HMS displays a low emission performance in the infrared band, with the emissivity less than 0.27 from 3 to 14 µm. It is believed that our proposal may find the application of multispectral stealth technology.