Advances in gum-based hydrogels and their environmental applications.

Gum-based hydrogels (GBHs) have been widely employed in diverse water purification processes due to their environmental properties, and high absorption capacity. More desired properties of GBHs such as biodegradability, biocompatibility, material cost, simplicity of manufacture, and wide range of uses have converted them into promising materials in water treatment processes. In this review, we explored the application of GBHs to remove pollutants from contaminated waters. Water resources are constantly being contaminated by a variety of harmful effluents such as heavy metals, dyes, and other dangerous substances. A practical way to remove chemical waste from water as a vital component is surface adsorption. Currently, hydrogels, three-dimensional polymeric networks, are quite popular for adsorption. They have more extensive uses in several industries, including biomedicine, water purification, agriculture, sanitary products, and biosensors. This review will help the researcher to understand the research gaps and drawbacks in this field, which will lead to further developments in the future.

Chitosan-supported metal nanocatalysts for the reduction of nitroaromatics.

The second most abundant natural polymer in the earth's crust is chitosan (CS). The unique physical, chemical, structural, and mechanical features of this natural polymer have led to its increased application in a variety of fields such as medicine, catalysis, removal of pollutants, etc. To eliminate various pollutants, it is preferable to employ natural compounds as their use aids the removal of contaminants from the environment. Consequently, employing CS to eliminate contaminants is a viable choice. For this aim, CS can be applied as a template and support for metal nanoparticles (MNPs) and prevent the accumulation of MNPs as well as a reducing and stabilizing agent for the synthesis of MNPs. Among the pollutants present in nature, nitro compounds are an important and wide category of biological pollutants. 4-Nitrophenol (4-NP) is one of the nitro pollutants. There are different ways for the removal of 4-NP, but the best and most effective method for this purpose is the application of a metallic catalyst and a reducing agent. In this review, we report the recent developments regarding CS-supported metallic (nano)catalysts for the reduction of nitroaromatics such as nitrophenols, nitroaniline compounds, nitrobenzene, etc. in the presence of reducing agents. The metals investigated in this study include Ag, Au, Ni, Cu, Ru, Pt, Pd, etc.