Munition constituents: Preliminary sediment screening criteria for the protection of marine benthic invertebrates.

Sediment screening criteria for many munition constituents (MC) are not available in sources typically used in regulatory-driven ecological risk assessments for contaminated sediment sites. Preliminary sediment quality benchmarks (SQBs) for MC were developed for screening potential risks to marine benthic invertebrates at a munitions contaminated sediment site in Puget Sound, WA, USA. SQBs were developed for 2,4,6-trinitrotoluene (TNT) and 13 breakdown products; six other explosive nitroaromatic compounds and nitramines (e.g., RDX, HMX); and five propellants, plasticizers, and stabilizers. The SQBs were developed using freshwater and limited marine aquatic toxicity values (and hence are considered preliminary) and equilibrium partitioning theory to relate water concentrations of the compounds to sediment concentrations. The SQBs are derived from the lowest available aquatic toxicity values for aquatic invertebrates from published reviews, original studies, and database sources; ranges of logK(ow) and K(oc) values from published reviews and database sources, and some K(oc) values calculated from logK(ow). SQBs are presented for 25 MC as organic carbon-normalized values and as ranges of dry weight values for various levels of organic carbon content of sediments. Comparison of the preliminary SQBs with method detection limits and sample detection limits achieved at the contaminated sediment site demonstrates their utility in risk screening of benthic invertebrates.

Impact of offsite sediment transport and toxicity on remediation of a contaminated estuarine bay.

Sediment of Ostrich Bay, an arm of Dyes Inlet on Puget Sound, was historically contaminated with ordnance compounds from an onshore US Navy facility. An initial recommendation for a sediment cover to mitigate benthic risks was followed by studies of sediment transport and deposition to determine whether contaminated sediment from Dyes Inlet or other offsite sources in Puget Sound may contribute to Ostrich Bay impacts. A Sediment Trend Analysis (STA) identified net sediment transport pathways throughout the bay and inlet by examining changes in grain size distributions in multiple adjacent samples. Results indicated that fine-grained sedimentary material transports into and deposits throughout the Dyes Inlet system, with no erosion or transport out of Ostrich Bay. Echinoderm larvae mortality bioassay results were elevated in fine-grained sediments of both Ostrich Bay and Dyes Inlet. Ordnance compounds were undetected, and although sediment mercury concentrations were elevated at 0.48-1.4 mg/kg in both waterbodies, the relationship with toxicity was weak. Results of the studies and sedimentation modeling indicate that impacted sedimentary material deposits throughout the Dyes Inlet/Ostrich Bay system from unknown sources and will prevent natural recovery of Ostrich Bay as well as negate long-term effectiveness of active remedial measures. Stakeholders have recognized that remediation of the bay can be achieved only after the toxicity of depositing sediment decreases.