Electrically driven kinklike distorting waves in microsized liquid crystals.

Electrically driven kinklike distortion regimes in a microsized liquid crystal channel have been investigated both experimentally and analytically. Kinklike distortion waves were excited by the interaction between the electric field E and the gradient ∇n[over ̂] of the director field in a homogeneously aligned liquid crystal (HALC) channel. Having obtained the evolution of the normalized light intensity, which was recorded by the high-speed camera, the process of excitation and evolution of the traveling wave in the HALC channel was visualized for the first time. It was shown, based on a nonlinear extension of the classical Ericksen-Leslie theory, that in the case when the electric field E≫E_{th}, the flow of liquid crystal material completely stops and a new mechanism for converting the electric field arises in the form of the electrically driven distorting traveling kinklike wave, which can be excited in the LC channel, composed of 4-n-pentyl-4^{'}-cyanobiphenyl molecules.

Electrically driven nematic flow in microfluidic capillary with radial temperature gradient.

An electrically driven fluid pumping principle and a mechanism of kinklike distortion of the director field n[over ̂] in the microsized nematic volume has been described. It is shown that the interactions, on the one hand, between the electric field E and the gradient of the director's field ∇n[over ̂], and, on the other hand, between the ∇n[over ̂] and the temperature gradient ∇T arising in a homogeneously aligned liquid crystal microfluidic channel, confined between two infinitely long horizontal coaxial cylinders, may excite the kinklike distortion wave spreading along normal to both cylindrical boundaries. Calculations show that the resemblance to the kinklike distortion wave depends on the value of radially applied electric field E and the curvature of these boundaries. Calculations also show that there exists a range of parameter values (voltage and curvature of the inner cylinder) producing a nonstandard pumping regime with maximum flow near the hot cylinder in the horizontal direction.

Electrically driven nematic flow in microfluidic devices containing a temperature gradient.

Fluid pumping principle has been developed utilizing the interaction, on the one hand, between the electric field E and the gradient ∇n[over ̂] of the director's field, and, on the other hand, between the ∇n[over ̂] and the temperature ∇T gradient arising in a homogeneously aligned liquid crystal (HALC) microfluidic channel. Calculations, based upon the nonlinear extension of the classical Ericksen-Leslie theory, with accounting the entropy balance equation, show that due to the coupling among the ∇T, ∇n,[over ̂] and E in the HALC microfluidic channel the horizontal flow v=v_{x}i[over ̂]=ui[over ̂] may be excited. The direction and magnitude of v is influenced both by the heat flux q across the microfluidic channel and the strength of the electric field E. The results of calculations showed that the dependence of the maximum value of the equilibrium velocity distribution |u_{max}(E/E_{th})| across the LC channel versus electric field E/E_{th} is characterized by maximum value at E/E_{th}=2.0. In the case when the electric field E≫E_{th}, the horizontal flow of the LC material completely stops and a novel mechanism of converting of the electric field in the form of the kinklike wave reorientation of the director field n[over ̂] can be excited in the LC channel.

Photoinduced reordering in thin azo-dye films and light-induced reorientation dynamics of the nematic liquid-crystal easy axis.

We theoretically study the kinetics of photoinduced reordering triggered by linearly polarized (LP) reorienting light in thin azo-dye films that were initially illuminated with LP ultraviolet pumping beam. The process of reordering is treated as a rotational diffusion of molecules in the light intensity-dependent mean-field potential. The two-dimensional diffusion model which is based on the free energy rotational Fokker-Planck equation and describes the regime of in-plane reorientation is generalized to analyze the dynamics of the azo-dye order parameter tensor at varying polarization azimuth of the reorienting light. It is found that, in the photosteady state, the intensity of LP reorienting light determines the scalar order parameter (the largest eigenvalue of the order parameter tensor), whereas the steady state orientation of the corresponding eigenvector (the in-plane principal axis) depends solely on the polarization azimuth. We show that, under certain conditions, reorientation takes place only if the reorienting light intensity exceeds its critical value. Such threshold behavior is predicted to occur in the bistability region provided that the initial principal axis lies in the polarization plane of reorienting light. The model is used to interpret the experimental data on the light-induced azimuthal gliding of the liquid-crystal easy axis on photoaligned azo-dye substrates.

Electrically assisted light-induced azimuthal gliding of the nematic liquid-crystal easy axis on photoaligned substrates.

We study azimuthal gliding of the easy axis that occurs in nematic liquid crystals brought in contact with the photoaligned substrate (initially irradiated azo-dye film) under the action of reorienting UV light combined with in-plane electric field. For irradiation with the linearly polarized light, dynamics of easy axis reorientation is found to be faster as compared to the case of nonpolarized light. Another effect is that it slows down with the initial irradiation dose used to prepare the azo-dye film. This effect is interpreted by using the previously suggested phenomenological model. We present the theoretical results computed by solving the torque balance equations of the model that agree very well with the experimental data.