Noisy three-player dilemma game: robustness of the quantum advantage.

Games involving quantum strategies often yield higher payoff. Here, we study a practical realization of the three-player dilemma game using the superconductivity-based quantum processors provided by IBM Q Experience. We analyze the persistence of the quantum advantage under corruption of the input states and how this depends on parameters of the payoff table. Specifically, experimental fidelity and error are observed not to be properly anti-correlated; i.e., there are instances where a class of experiments with higher fidelity yields a greater error in the payoff. Further, we find that the classical strategy will always outperform the quantum strategy if corruption is higher than 50%.

Excited state behavior of pyrrole 2-carboxyldehyde: theoretical and experimental study.

Photophysical and photochemical dynamics of excited state proton transfer reaction have been reported for Pyrrole 2-carboxyldehyde (PCL). Experimental and theoretical observations yield all possible signatures of intramolecular and intermolecular proton transfer in an excited state. Dual emission (~325 nm, ~375 nm) on photo excitation indicates the existence of more than one species in an excited state. Computed reaction pathway and two-dimensional potential energy profile in the ground state reveals a single minimum corresponding to normal form (E). Dual minima in excited state energy profile shows the existence of two species, one normal and other zwitterionic (Z*) species. A large Stokes shifted emission at ~375 nm in hydrocarbon medium reveals the existence of zwitterionic species due to Excited state intramolecular proton transfer (ESI(ra)PT). Excited State Intermolecular proton transfer (ESI(er)PT) is observed in a hydroxylic environment around 430-490 nm. pH variation in hydroxylic medium suggests the formation of anion (A((-))) from Z*.