Electrodeposited PEDOT:PSS-Al2O3 Improves the Steady-State Efficiency of Inverted Perovskite Solar Cells.

The atomic layer deposition (ALD) of Al2O3 between perovskite and the hole transporting material (HTM) PEDOT:PSS has previously been shown to improve the efficiency of perovskite solar cells. However, the costs associated with this technique make it unaffordable. In this work, the deposition of an organic-inorganic PEDOT:PSS-Cl-Al2O3 bilayer is performed by a simple electrochemical technique with a final annealing step, and the performance of this material as HTM in inverted perovskite solar cells is studied. It was found that this material (PEDOT:PSS-Al2O3) improves the solar cell performance by the same mechanisms as Al2O3 obtained by ALD: formation of an additional energy barrier, perovskite passivation, and increase in the open-circuit voltage (Voc) due to suppressed recombination. As a result, the incorporation of the electrochemical Al2O3 increased the cell efficiency from 12.1% to 14.3%. Remarkably, this material led to higher steady-state power conversion efficiency, improving a recurring problem in solar cells.

Quantum tunneling theory of Cooper pairs as bosonic particles.

We propose a simple phenomenological theory for quantum tunneling of Cooper pairs, in superconductor/insulator/superconductor tunnel junctions, for a regime where the system can be modeled as bosonic particles. Indeed, provided there is an absence of quasiparticle excitations (fermions), our model reveals a rapid increase in tunneling current, around zero bias voltage, which rapidly saturates. This manifests as a zero bias conductance peak that strongly depends on the superconductors temperature in a non-monotonic way. This low energy tunneling of Cooper pairs could serve as an alternative explanation for a number of tunneling experiments where zero bias conductance peak has been observed.

Rational Design of Photo-Electrochemical Hybrid Devices Based on Graphene and Chlamydomonas reinhardtii Light-Harvesting Proteins.

Dye-sensitized solar cells (DSSCs) have been highlighted as the promising alternative to generate clean energy based on low pay-back time materials. These devices have been designed to mimic solar energy conversion processes from photosynthetic organisms (the most efficient energy transduction phenomenon observed in nature) with the aid of low-cost materials. Recently, light-harvesting complexes (LHC) have been proposed as potential dyes in DSSCs based on their higher light-absorption efficiencies as compared to synthetic dyes. In this work, photo-electrochemical hybrid devices were rationally designed by adding for the first time Leu and Lys tags to heterologously expressed light-harvesting proteins from Chlamydomonas reinhardtii, thus allowing their proper orientation and immobilization on graphene electrodes. The light-harvesting complex 4 from C. reinhardtii (LHC4) was initially expressed in Escherichia coli, purified via affinity chromatography and subsequently immobilized on plasma-treated thin-film graphene electrodes. A photocurrent density of 40.30 ± 9.26 µA/cm2 was measured on devices using liquid electrolytes supplemented with a phosphonated viologen to facilitate charge transfer. Our results suggest that a new family of graphene-based thin-film photovoltaic devices can be manufactured from rationally tagged LHC proteins and opens the possibility to further explore fundamental processes of energy transfer for biological components interfaced with synthetic materials.

Coercive field enhancement in Co nanodisks: single-domain to vortex switching.

Magnetic multi-layered nanodisks (ND) show great promise as these are relatively easy to assemble and control, facilitating biological and storage applications. In the present work, Ti/Co/Nb ND were fabricated with a varying Co layer thickness between 6 and 14 nm. Using vibrating sample magnetometry and micromagnetic simulations (OOMMF), their magnetic properties were investigated. Our results reveal a peak in coercive field at a critical thickness that separates the two magnetic phases; single domain and vortex phase. This peak is characterized by a substantially larger coercive field and allows to establish an explicit phase diagram as a function of diameter and thickness of the ND. This opens the possibility to investigate such enhancement in other ferromagnetic materials too.

Enhancement of the transversal magnetic optic Kerr effect: Lock-in vs. hysteresis method.

The lock-in amplifier is often used to study the enhancement of the magneto-optical Kerr effect (MOKE) in the presence of plasmon resonances. In the present work we show that it is possible to investigate such effect replacing the lock-in amplifier by a compensator, filter, and differential amplifier. This allows us to extract the full hysteresis loop in and out of the resonance without the need of a lock-in amplifier. Our results demonstrate these two setups are equivalent to study the enhancement of the transversal MOKE (T-MOKE) in magnetoplasmonic systems.