Coagulation-adsorption-oxidation for removing dyes from tannery wastewater.

Dye removal from tannery wastewater is now a great concern given the ramifications for the environment in which the effluent ends up. Recently, the application of tannery solid waste as a byproduct to remove pollutants from tannery wastewater has garnered increasing attention. This study aims to extract biochar from tannery liming sludge for the removal of dye from wastewater. The activated (600 ºC) biochar was characterized by SEM (Scanning Electron Microscope), EDS (Energy Dispersive Spectroscopy), FTIR (Fourier Transform Infrared Spectroscopy), and surface area analysis utilizing the BET (Brunauer-Emmett-Teller) method and pHpzc (point of zero charges) analysis. The surface area and pHpzc of the biochar were determined as 9.29 m2/g and 8.7, respectively. The batch-wise coagulation-adsorption-oxidation was investigated for its efficacy in dye removal. The optimized conditions were as follows: the efficiency of dye, BOD (Biochemical Oxygen Demand) and COD (Chemical Oxygen Demand) were attained at 94.9%, 95.7% and 93.5%, respectively. SEM, EDS, and FTIR analyses before and after adsorption revealed that the derived biochar could adsorb dye from tannery wastewater. The adsorption behavior of the biochar fitted well to the Freundlich isotherm (R2 = 0.9987) and Pseudo 2nd order (R2 = 0.9996) kinetic model. This investigation provides a new dimension for state-of-the-art utilization of tannery solid waste as a feasible strategy to remove dye from tannery wastewater.

Composting of limed fleshings generated in a tannery: sustainable waste management.

In tanneries, limed fleshing is an unavoidable waste generated in beamhouse operation. Proper management of limed fleshing with protein, fat, lime, and sulfide will help to protect the natural environment and at least reduce the pollution that ends up in it. In this study, excluding any pretreatment, limed fleshing is used for compost production. Chopped and mixed limed fleshing with chicken manure, cow dung, and sawdust was heaped onto a horizontal bamboo frame. Three composting heaps were fabricated weighing 720, 700, and 760 kg. The turning of composting materials in the heaps causes temperature changes in the thermophilic range. The thermophilic temperatures in these heaps were 69.07 °C (heap 1), 69.9 °C (heap 2), and 69.19 °C (heap 3) which ensured the death of the pathogenic organism. The quality of compost was assessed based on the nutrients-nitrogen (N), phosphorous (P), potassium (K), and sulfur (S) content. NPKS in the compost fulfils the requirements of the investigated materials as compost. The largest amounts of metals- zinc (Zn), copper (Cu), chromium (Cr), lead (Pb), and nickel (Ni) of the compost detected in the heaps were, respectively, 200.3, 37.4, 20.3, 12.0, and 3.9 mg/kg. Cadmium (Cd) in the compost was below the detection limit. Scanning electron microscope (SEM) photographs show the decomposing of composting materials. This study indicates that limed fleshing can be converted into nutrient-enriched compost without any pretreatment. Using an easy, simple, and adaptable technique could reduce the volume of solid waste generated in the tannery to reduce environmental pollution.

Bio-intervention phyto-based material for raw goatskin preservation: a cleaner-sustainable approach.

The regular practice of using sodium chloride to preserve raw animal skin triggers increasing salinity and total dissolved solids (TDS) in the surface and groundwater during rehydration soaking operations. The process disrupts the lives of animals, plants, and human beings. This paper is focused on the phyto-based short-term preservation of goatskin to reduce salinity in tannery soaking operations. The indigenous Persicaria hydropiper leaf was investigated to assess the preservation of animal skin to diminish salinity and TDS of tannery soaking wastewater. Methanol-extracted leaf was characterized by GC-MS and FTIR for chemical composition analysis and affiliated functional groups. Fresh goatskins were preserved at the preliminary, laboratory, and pilot-scale scenarios to establish the best possible mixture and monitor the moisture and nitrogen content, shrinkage temperature, microorganism analysis, and pollution load at each level. The processed leathers derived from the preserved skins with an optimal mixture of 10% leaf paste with 8% salt and conventional 50% salt were tested for their physical strength. Finally, the modification in fiber structure due to the varieties of preserving chemicals was evaluated through a scanning electron microscope (SEM) and detected insignificant variation of leather fibers. The findings reported in this study can be applied to the industrial level and remove certain amounts of salinity and TDS from tannery soaking wastewater.

The environmental impacts of heavy metals in soil, certain plants and wastewater near industrial area of Brahmanbaria, Bangladesh.

At various locations around the world, environments are now becoming greatly polluted by heavy metals, while damage is being done to soil and aquatic life with serious implications for humanity as well. Once heavy metals enter the ecosystem, they persist for a long time, and they are very difficult to eliminate. Discharging of industrial wastes enriched with heavy metals substantially pollutes the soil, water, and air. This study investigated the levels of heavy metals around the industrial area of Brahmanbaria, which is located in Chittagong Division, Bangladesh. Samples of soil, wastewater, vegetable, and grass were collected from the industrial area. The heavy metals were quantified using atomic absorption spectroscopy. The heavy metals found in soil were chromium (Cr) 8.2-18.8, lead (Pb) 3.5-18.3, copper (Cu) 4.6-10.8, zinc (Zn) 48.5-273.4, nickel (Ni) 10.06-26.9, and cadmium (Cd) 0.2 mg/kg, respectively. The metal contents in the wastewater were Cr 0.03-0.5, Pb 0.01-0.05, Cu 0.01-0.02, Zn 0.6-11.2, Ni 0.03-0.14, and Cd 0.003 mg/L, respectively. The metal contents in vegetable and grass were Cr 81.5-247.8, Pb 10.3-34.1, Cu 5.5-6.3, Zn 419.8-435.3, and Ni 8.7-15.5 mg/kg, respectively. The amount of metal in the soil, wastewater, and vegetables and grass followed the sequences: Zn > Cr > Ni > Pb > Cu > Cd, Zn > Cr > Ni > Pb > Cu > Cd, and Zn > Cr > Pb > Ni > Cu, respectively. Compared to the WHO guidelines, the soil in the study area was not polluted with Pb, Cu, and Cd but was moderately polluted with Cr, Zn, and Ni. Continual accumulation of metals in the soil, vegetables and grass could pose a serious risk to the environment as well as many life forms.