1.
Chem Commun (Camb)
; 52(2): 362-5, 2016 Jan 07.
Artigo
em Inglês
| MEDLINE
| ID: mdl-26521722
RESUMO
A method for enantioselective hydrogenation of cyclic imines with gaseous hydrogen has been developed. Easily accessible Noyori-Ikariya Ru(II) and Rh(III) complexes can be used directly without an inert atmosphere. Substrate activation has been achieved by trifluoroacetic acid. A new hydroxyl-functionalized complex is reported, showing high activity in transfer hydrogenation.