Vinegar residue biochar: A possible conditioner for the safe remediation of alkaline Pb-contaminated soil.

A better understanding how to modulate alkaline soil-plant systems with lead (Pb) toxicity with by vinegar residue biochar is important for the remediation of Pb-contaminated soil. Leaching column and pot experiments were conducted to investigate the effect of vinegar residue biochar on Pb speciation, soil properties, and plant growth under Pb stress. The results indicate that biochar could effectively decrease the exchangeable and carbonated-bound Pb but increase the Fe-Mn oxide and residue fractions in the soil with Pb at 500 mg kg-1. Biochar did not effectively immobilize Pb in the soil with Pb at 1000 mg kg-1. After leaching, biochar evidently increased the organic carbon and dissolved organic carbon content of the soil, but slightly affected the pH, cation exchange capacity and carbonate content. The biochar addition at 0.5% had no significant effect on soil aggregates, and biochar at 2.0% and 5.0% significantly decreased soil aggregate stability. The dry weight and soluble protein content of pak choi (Brassica chinensis L.) increased with biochar treatment. Lead assimilation by plants was inhibited by the decreased availability of Pb in biochar-treated soils. Soil enzymes activities also significantly increased, then facilitated biochemical reactions in the soil environment. The applied biochar has shown an important role in mitigating Pb toxicity by increasing the soil organic carbon, dissolved organic carbon content, enzyme activities, and plant growth. The low dose biochar (0.5-2.0%) are recommended as references for subsequent experiments, especially in alkaline loam soil.

Vinegar residue supported nanoscale zero-valent iron: Remediation of hexavalent chromium in soil.

A composite material comprising of nanoscale zero-valent iron (nZVI) supported on vinegar residue (nZVI@VR) was prepared and applied for remediation of soils contaminated by hexavalent chromium (Cr(VI)). Sedimentation test results revealed that the nZVI@VR displayed enhanced stability in comparison to the bare-nZVI. Remediation experiments exhibited the immobilization efficiency of Cr(VI) and Crtotal was 98.68% and 92.09%, respectively, when using 10 g nZVI@VR (nZVI 5%) per 200 g Cr-contaminated soil (198.20 mg kg-1 Cr(VI), 387.24 mg kg-1 Crtotal) after two weeks of incubation. Further analyses demonstrated that almost all the exchangeable Cr was transformed into Fe-Mn oxide bound and organic matter bound. Moreover, the application of nZVI@VR enhanced soil organic carbon content and reduced redox potential. After granulation, the immobilization efficiency of Cr(VI) and Crtotal achieved 100% and 91.83% at a dosage of 10% granular nZVI@VR. Granular nZVI@VR also accelerated the transform of more available Cr (exchangeable and bound to carbonates) into less available fractions (Fe-Mn oxide bound and organic matter bound), thus resulting in a remarkable reduction in the Cr bioavailability. These results prove that nZVI@VR can be an effective remediation reagent for soils contaminated by Cr(VI).

Remediation of cadmium contaminated water and soil using vinegar residue biochar.

This study investigated a new biochar produced from vinegar residue that could be used to remediate cadmium (Cd)-contaminated water and soil. Aqueous solution adsorption and soil incubation experiments were performed to investigate whether a biochar prepared at 700 °C from vinegar residue could efficiently adsorb and/or stabilize Cd in water and soil. In the aqueous solution adsorption experiment, the Cd adsorption process was best fitted by the pseudo-second-order kinetic and Freundlich isotherm models. If the optimum parameters were used, i.e., pH 5 or higher, a biochar dosage of 12 g L-1, a 10 mg L-1 Cd initial concentration, and 15-min equilibrium time, at 25 °C, then Cd removal could reach about 100%. The soil incubation experiment evaluated the biochar effects at four different application rates (1, 2, 5, and 10% w/w) and three Cd contamination rates (0.5, 1, and 2.5 mg kg-1) on soil properties and Cd fractionation. Soil pH and organic matter increased after adding biochar, especially at the 10% application rate. At Cd pollution levels of 1.0 or 2.5 mg kg-1, a 10% biochar application rate was most effective. At 0.5 mg Cd kg-1 soil, a 5% biochar application rate was most efficient at transforming the acid extractable and easily reducible Cd fractions to oxidizable and residual Cd. The results from this study demonstrated that biochar made from vinegar residue could be a new and promising alternative biomass-derived material for Cd remediation in water and soil.

Biosurfactant-enhanced removal of o,p-dichlorobenzene from contaminated soil.

Surfactant-enhanced remediation is less applicable for the treatment of dichlorobenzene (DCB)-contaminated soil. In this study, water solubility enhancements of o-dichlorobenzene (o-DCB) and p-dichlorobenzene (p-DCB) by micellar solutions of biosurfactants (saponin, alkyl polyglycoside) and chemically synthetic surfactant (Tween 80) were measured and compared. Solubilities of o,p-DCB in water were greatly enhanced in a linear fashion by each of Tween 80, saponin, and alkyl polyglycoside. Solubility enhancement efficiencies of surfactants followed the order of Tween 80 > saponin > alkyl polyglycoside. However, the ex situ soil washing experiment demonstrated the opposite result. The removal efficiency of o,p-DCB by biosurfactant saponin and alkyl polyglycoside was higher than that of chemically synthetic surfactant Tween 80 in contaminated soil. This difference may be due to the different adsorption behaviors of the surfactants onto soil. In addition, elution kinetics for o,p-DCB were relatively fast, with apparent elution equilibrium reached within 360 min, and can be described by a pseudo first-order kinetic equation. The elution process of o,p-DCB in soil-aqueous systems obeyed four-parameter biphasic first-order kinetic model including rapid and slow phases. The results confirmed potential application of saponin and alkyl polyglycoside in elution solution for enhanced remediation of DCB-contaminated soil.

Surfactant flushing remediation of o-dichlorobenzene and p-dichlorobenzene contaminated soil.

Surfactant-enhanced remediation is used to treat dichlorobenzene (DCB) contaminated soil. In this study, soil column experiments were conducted to investigate the removal efficiencies of o-dichlorobenzene (o-DCB) and p-dichlorobenzene (p-DCB) from contaminated soil using micellar solutions of biosurfactants (saponin, alkyl polyglycoside) compare to a chemically synthetic surfactant (Tween 80). Leachate was collected and analyzed for o-DCB and p-DCB content. In addition, soil was analyzed to explore the effect of surfactants on soil enzyme activities. Results showed that the removal efficiency of o-DCB and p-DCB was highest for saponin followed by alkyl polyglycoside and Tween 80. The maximum o-DCB and p-DCB removal efficiencies of 76.34% and 80.43%, respectively, were achieved with 4 g L-1 saponin solution. However, an opposite result was observed in the cumulative mass of o-DCB and p-DCB in leachate. The cumulative extent of o-DCB and p-DCB removal by the biosurfactants saponin and alkyl polyglycoside was lower than that of the chemically synthetic surfactant Tween 80 in leachate. Soil was also analyzed to explore the effect of surfactants on soil enzyme activities. The results indicated that surfactants were potentially effective in facilitating soil enzyme activities. Thus, it was confirmed that the biosurfactants saponin and alkyl polyglycoside could be used for remediation of o-DCB and p-DCB contaminated soil.

Immobilization of lead by application of soil amendment produced from vinegar residue, stainless steel slag, and weathered coal.

This paper presents a new soil amendment used for immobilization of soil Pb, produced from vinegar residue, stainless steel slag, and weathered coal. The pH value measuring, granulation and adsorption experiments were carried out to determine the optimal composition of soil amendment. Optimizing soil amendment B2 was composed of vinegar residue, weathered coal (humic acid 61.53 wt%), and stainless steel slag with the ratio of 80∶16∶4, and particle size was in the range of 2-4 mm. In the leaching column experiment, B2 addition reduced the Pb release from the soil as well as increasing leachate pH and decreasing the bioavailable Pb concentration. The leachate Pb concentration decreased with lengthened leaching time under lower pH, but such a phenomenon disappeared in the rebounding period. Compared to control, the DTPA extractable Pb content in soil decreased by 12.41, 13.20, and 8.78% with the B2 addition amount of 1.00, 2.00, and 2.00 wt%, respectively. In addition, the total Pb content of each soil layer generally rose as B2 addition increased. It was concluded that application of B2 led to lower transport and transformation of Pb in soil. Based on the single chemical extraction, the environmental risk of Pb was decreased after application of B2. Meanwhile, soil amendment was also a new way to recycle vinegar residue, stainless steel slag, and weathered coal.