RESUMO
Because disease pandemics can accelerate rapidly in areas with limited clean-water access, a portable greywater reuse system may be useful to provide wash water at emergency health care units. In this study, a novel fed-batch (hybrid continuous-batch flow) net-zero water (NZW), or nearly closed-loop, reuse system comprising screening, 5 µm filter, and ozone-UV advanced oxidation was designed, constructed, and tested for performance with simulated and actual human showers. Water quality was tested for compliance with US drinking water standards, total organic carbon < 0.5 mg/L, and pathogen inactivation including 12 log10 virus, 10 log10 protozoa, and 9 log10 bacteria as has been recommended for direct potable reuse. Energy, operation, and maintenance requirements were also evaluated, along with the system's capacity to handle shock events such as unintentional contamination with urine. Design goals were achieved without the addition of GAC point-of-use filter, except compliance with bromate and nitrate drinking water standards, which were met only for temporary use of up to three years per person. A capacity of 32 showers/day at 1920 W continuous power is projected, without generation of potentially-infectious concentrate. To avoid the further increase in system weight and energy demand needed to address urine input, future integrated urine diversion and collection, and system drain-and-fill following detection of urine in recycled water by electrical conductivity, are suggested for the field unit. Field testing is recommended. Further research should focus on potential need for bromate/nitrate mitigation, and longer-term study of microbiological inactivation.
RESUMO
Denitrifying membrane bioreactors (MBRs) are being found useful in water reuse treatment systems, including net-zero water (nearly closed-loop), non-reverse osmosis-based, direct potable reuse (DPR) systems. In such systems nitrogen may need to be controlled in the MBR to meet the nitrate drinking water standard in the finished water. To achieve efficient nitrification and denitrification, the addition of alkalinity and external carbon may be required, and control of the carbon feed rate is then important. In this work, an onsite, two-chamber aerobic nitrifying/denitrifying MBR, representing one unit process of a net-zero water, non-reverse osmosis-based DPR system, was modeled as a basis for control of the MBR internal recycling rate, aeration rate, and external carbon feed rate. Specifically, a modification of the activated sludge model ASM2dSMP was modified further to represent the rate of recycling between separate aerobic and anoxic chambers, rates of carbon and alkalinity feed, and variable aeration schedule, and was demonstrated versus field data. The optimal aeration pattern for the modeled reactor configuration and influent matrix was found to be 30 min of aeration in a 2 h cycle (104 m3 air/d per 1 m3/d average influent), to ultimately meet the nitrate drinking water standard. Optimal recycling ratios (inter-chamber flow to average daily flow) were found to be 1.5 and 3 during rest and mixing periods, respectively. The model can be used to optimize aeration pattern and recycling ratio in such MBRs, with slight modifications to reflect reactor configuration, influent matrix, and target nitrogen species concentrations, though some recalibration may be required.
